Reference Type | Journal (article/letter/editorial) |
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Title | The system Pd-Fe-Ni-S at 900 and 725°C |
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Journal | Mineralogical Magazine | ISSN | 0026-461X |
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Authors | Makovicky, Emil | Author |
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Karup-Møller, Sven | Author |
Year | 1995 (December) | Volume | 59 |
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Issue | 397 |
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Publisher | Mineralogical Society |
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Download URL | https://rruff.info/doclib/MinMag/Volume_59/59-397-685.pdf+ |
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DOI | doi:10.1180/minmag.1995.059.397.11Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 2698 | Long-form Identifier | mindat:1:5:2698:1 |
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GUID | 0 |
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Full Reference | Makovicky, Emil, Karup-Møller, Sven (1995) The system Pd-Fe-Ni-S at 900 and 725°C. Mineralogical Magazine, 59 (397) 685-702 doi:10.1180/minmag.1995.059.397.11 |
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Plain Text | Makovicky, Emil, Karup-Møller, Sven (1995) The system Pd-Fe-Ni-S at 900 and 725°C. Mineralogical Magazine, 59 (397) 685-702 doi:10.1180/minmag.1995.059.397.11 |
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In | (1995, December) Mineralogical Magazine Vol. 59 (397) Mineralogical Society |
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Abstract/Notes | AbstractThe system Pd-Fe-Ni-S was studied at 900 and 725°C by means of dry condensed charges. At both temperatures it is dominated by the phase relationships involving sulphide melt. Pd-Fe-Ni alloys with broad miscibility primarily coexist with the melt; they are relatively enriched in Pd, whereas the associated melt is enriched in Ni. With decreasing temperature the melt recedes from Fe-rich regions. The incompatibility of PdS (extensive solid solution with Ni) and mss at 900°C is replaced by their co-crystallization (± disulphide(s) of Ni,Fe or ± sulphide melt) at 725°C The Ni/Fe ratio in the melt changes regularly against that in mss with increasing S fugacity and Pd contents in these two phases. (Ni,Fe)3±xS2 and Pd4S play important roles at 725°C. The data offer an array of distribution coefficients and solubility values suitable for geological interpretations. |
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