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Makovicky, Emil, Karup-Møller, Sven (1995) The system Pd-Fe-Ni-S at 900 and 725°C. Mineralogical Magazine, 59 (397) 685-702 doi:10.1180/minmag.1995.059.397.11

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Reference TypeJournal (article/letter/editorial)
TitleThe system Pd-Fe-Ni-S at 900 and 725°C
JournalMineralogical MagazineISSN0026-461X
AuthorsMakovicky, EmilAuthor
Karup-Møller, SvenAuthor
Year1995 (December)Volume59
Issue397
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_59/59-397-685.pdf+
DOIdoi:10.1180/minmag.1995.059.397.11Search in ResearchGate
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Mindat Ref. ID2698Long-form Identifiermindat:1:5:2698:1
GUID0
Full ReferenceMakovicky, Emil, Karup-Møller, Sven (1995) The system Pd-Fe-Ni-S at 900 and 725°C. Mineralogical Magazine, 59 (397) 685-702 doi:10.1180/minmag.1995.059.397.11
Plain TextMakovicky, Emil, Karup-Møller, Sven (1995) The system Pd-Fe-Ni-S at 900 and 725°C. Mineralogical Magazine, 59 (397) 685-702 doi:10.1180/minmag.1995.059.397.11
In(1995, December) Mineralogical Magazine Vol. 59 (397) Mineralogical Society
Abstract/NotesAbstractThe system Pd-Fe-Ni-S was studied at 900 and 725°C by means of dry condensed charges. At both temperatures it is dominated by the phase relationships involving sulphide melt. Pd-Fe-Ni alloys with broad miscibility primarily coexist with the melt; they are relatively enriched in Pd, whereas the associated melt is enriched in Ni. With decreasing temperature the melt recedes from Fe-rich regions. The incompatibility of PdS (extensive solid solution with Ni) and mss at 900°C is replaced by their co-crystallization (± disulphide(s) of Ni,Fe or ± sulphide melt) at 725°C The Ni/Fe ratio in the melt changes regularly against that in mss with increasing S fugacity and Pd contents in these two phases. (Ni,Fe)3±xS2 and Pd4S play important roles at 725°C. The data offer an array of distribution coefficients and solubility values suitable for geological interpretations.


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