Glasser, L. S. Dent (1979) Non-existent silicates. Zeitschrift für Kristallographie - Crystalline Materials, 149 (3-4) 291 doi:10.1524/zkri.1979.149.3-4.291
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Non-existent silicates | ||
| Journal | Zeitschrift für Kristallographie - Crystalline Materials | ||
| Authors | Glasser, L. S. Dent | Author | |
| Year | 1979 (January 1) | Volume | 149 |
| Issue | 3-4 | ||
| Publisher | Walter de Gruyter GmbH | ||
| DOI | doi:10.1524/zkri.1979.149.3-4.291Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 109498 | Long-form Identifier | mindat:1:5:109498:9 |
| GUID | 0 | ||
| Full Reference | Glasser, L. S. Dent (1979) Non-existent silicates. Zeitschrift für Kristallographie - Crystalline Materials, 149 (3-4) 291 doi:10.1524/zkri.1979.149.3-4.291 | ||
| Plain Text | Glasser, L. S. Dent (1979) Non-existent silicates. Zeitschrift für Kristallographie - Crystalline Materials, 149 (3-4) 291 doi:10.1524/zkri.1979.149.3-4.291 | ||
| In | (1979, January) Zeitschrift für Kristallographie - Crystalline Materials Vol. 149 (3-4) Walter de Gruyter GmbH | ||
| Abstract/Notes | SummaryMany topologically possible silicate structures do not exist, and the reasons for this are considered. Limitations on the chemical compositions of anhydrous binary silicates are discussed and explained. The rarity of branched anions whose silicate tetrahedra do not all share the same number of corners is related to the (Lewis) basicity calculated for individual oxygen atoms in the structure. The concept of basicity is also used to explain why various hydrated silicates adopt their observed constitutions rather than other possible ones. | ||
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