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Chepurov, Aleksei, Sonin, Valery, Dereppe, Jean-Marie, Zhimulev, Egor, Chepurov, Anatoly (2020) How do diamonds grow in metal melt together with silicate minerals? An experimental study of diamond morphology. European Journal of Mineralogy, 32 (1) 41-55 doi:10.5194/ejm-32-41-2020

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Reference TypeJournal (article/letter/editorial)
TitleHow do diamonds grow in metal melt together with silicate minerals? An experimental study of diamond morphology
JournalEuropean Journal of Mineralogy
AuthorsChepurov, AlekseiAuthor
Sonin, ValeryAuthor
Dereppe, Jean-MarieAuthor
Zhimulev, EgorAuthor
Chepurov, AnatolyAuthor
Year2020 (January 16)Volume32
Issue1
PublisherCopernicus GmbH
Download URLhttps://ejm.copernicus.org/articles/32/41/2020/ejm-32-41-2020.pdf+
DOIdoi:10.5194/ejm-32-41-2020Search in ResearchGate
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Full ReferenceChepurov, Aleksei, Sonin, Valery, Dereppe, Jean-Marie, Zhimulev, Egor, Chepurov, Anatoly (2020) How do diamonds grow in metal melt together with silicate minerals? An experimental study of diamond morphology. European Journal of Mineralogy, 32 (1) 41-55 doi:10.5194/ejm-32-41-2020
Plain TextChepurov, Aleksei, Sonin, Valery, Dereppe, Jean-Marie, Zhimulev, Egor, Chepurov, Anatoly (2020) How do diamonds grow in metal melt together with silicate minerals? An experimental study of diamond morphology. European Journal of Mineralogy, 32 (1) 41-55 doi:10.5194/ejm-32-41-2020
In(2020) European Journal of Mineralogy Vol. 32 (1) Schweizerbart
Abstract/NotesAbstract. The origin and evolution of metal melts in the Earth's mantle and
their role in the formation of diamond are the subject of active discussion.
It is widely accepted that portions of metal melts in the form of
pockets can be a suitable medium for diamond growth. This raises
questions about the role of silicate minerals that form the walls of these
pockets and are present in the volume of the metal melt during the
growth of diamonds. The aim of the present work was to study the
crystallization of diamond in a complex heterogeneous system: metal-melt–basalt–carbon. The experiments were performed using a multianvil
high-pressure apparatus of split-sphere type (BARS) at a pressure of 5.5 GPa and a temperature of 1500 ∘C. The results demonstrated
crystallization of diamond in metal melt together with garnet and
clinopyroxene, whose chemical compositions are similar to those of eclogitic
inclusions in natural diamond. We show that the presence of silicates in the
crystallization medium does not reduce the chemical ability of metal melts
to catalyze the conversion of graphite into diamond, and, morphologically,
diamond crystallizes mainly in the form of a cuboctahedron. When the content
of the silicate material in the system exceeds 5 wt %, diamond forms
parallel-growth aggregates, but 15 wt % of silicate phases block the
crystallization chamber, preventing the penetration of metallic melt into
them, thus interrupting the growth of diamond. We infer that the studied
mechanism of diamond crystallization can occur at lower-mantle conditions
but could also have taken place in the ancient continental mantle of the
Earth, under reducing conditions that allowed the stability of Fe–Ni melts.


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