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Koshy, K. M., Tidwell, Thomas T. (1980) Solvolytic reactivity of .alpha.-trifluoromethylcarbinyl sulfonates. Correlation of rate retardation by electron-withdrawing substituents and solvent participation in tertiary substrates. Journal Of The American Chemical Society, 102 (3) 1216-1218 doi:10.1021/ja00523a077

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Reference TypeJournal (article/letter/editorial)
TitleSolvolytic reactivity of .alpha.-trifluoromethylcarbinyl sulfonates. Correlation of rate retardation by electron-withdrawing substituents and solvent participation in tertiary substrates
JournalJournal Of The American Chemical Society
AuthorsKoshy, K. M.Author
Tidwell, Thomas T.Author
Year1980 (January)Volume102
Issue3
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00523a077Search in ResearchGate
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Mindat Ref. ID1366346Long-form Identifiermindat:1:5:1366346:9
GUID0
Full ReferenceKoshy, K. M., Tidwell, Thomas T. (1980) Solvolytic reactivity of .alpha.-trifluoromethylcarbinyl sulfonates. Correlation of rate retardation by electron-withdrawing substituents and solvent participation in tertiary substrates. Journal Of The American Chemical Society, 102 (3) 1216-1218 doi:10.1021/ja00523a077
Plain TextKoshy, K. M., Tidwell, Thomas T. (1980) Solvolytic reactivity of .alpha.-trifluoromethylcarbinyl sulfonates. Correlation of rate retardation by electron-withdrawing substituents and solvent participation in tertiary substrates. Journal Of The American Chemical Society, 102 (3) 1216-1218 doi:10.1021/ja00523a077
In(1980, January) Journal Of The American Chemical Society Vol. 102 (3) American Chemical Society (ACS)

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KOSHY, K. M., TIDWELL, T. T. (1980) ChemInform Abstract: SOLVOLYTIC REACTIVITY OF α-TRIFLUOROMETHYLCARBINYL SULFONATES. CORRELATION OF RATE RETARDATION BY ELECTRON-WITHDRAWING SUBSTITUENTS AND SOLVENT PARTICIPATION IN TERTIARY SUBSTRATES. Chemischer Informationsdienst, 11 (19) doi:10.1002/chin.198019089
Allen, Annette D., Jansen, Michael P., Koshy, Kalavelil M., Mangru, Nevindra N., Tidwell, Thomas T. (1982) Solvolytic reactivity of 1-trifluoromethyl-1-phenylethyl tosylate. Correlation of substituent effects in the formation of highly destabilized carbonium ions. Journal Of The American Chemical Society, 104 (1) 207-211 doi:10.1021/ja00365a037
Chwang, Willy K., Knittel, P., Koshy, K. M., Tidwell, Thomas T. (1977) Kinetics of acid-catalyzed hydration of 1,3-butadienes and vinyl halides. Correlation of the reactivity of vinyl alkenes and aryl alkenes. Journal Of The American Chemical Society, 99 (10) 3395-3401 doi:10.1021/ja00452a035
Paddon-Row, Michael N., Santiago, Cielo, Houk, K. N. (1980) Possibility of .pi.-electron donation by the electron-withdrawing substituents CN, CHO, CF3, and +NH3. Journal Of The American Chemical Society, 102 (21) 6561-6563 doi:10.1021/ja00541a033
ALLEN, A. D., JANSEN, M. P., KOSHY, K. M., MANGRU, N. N., TIDWELL, T. T. (1982) ChemInform Abstract: SOLVOLYTIC REACTIVITY OF 1-TRIFLUOROMETHYL-1-PHENYLETHYL TOSYLATE. CORRELATION OF SUBSTITUENT EFFECTS IN THE FORMATION OF HIGHLY DESTABILIZED CARBONIUM IONS. Chemischer Informationsdienst, 13 (16) doi:10.1002/chin.198216112
Jansen, Michael P., Koshy, Kalavelil M., Mangru, Nevindra N., Tidwell, Thomas T. (1981) Solvolysis of 2-(trifluoromethyl)-2-propyl trifluoromethanesulfonate. Solvent, salt, and .beta.-deuterium isotope effects. Substituent effect of a strongly deactivating group and rate-limiting solvent-assisted elimination. Journal Of The American Chemical Society, 103 (13) 3863-3867 doi:10.1021/ja00403a040
Allen, Annette D., Kanagasabapathy, V. M., Tidwell, Thomas T. (1985) Solvolysis of 1-arylethyl tosylates. Kinetic and stereochemical tests for solvent participation. Journal Of The American Chemical Society, 107 (15) 4513-4519 doi:10.1021/ja00301a023
Allen, Annette D., Kanagasabapathy, V. M., Tidwell, Thomas T. (1983) Doubly destabilized carbocations. Unexpectedly high reactivity in formation of carbocation intermediates with two destabilizing substituents. Journal Of The American Chemical Society, 105 (18) 5961-5962 doi:10.1021/ja00356a065
Allen, Annete D., Sumonja, Mirjana, Tidwell, Thomas T. (1997) Solvolytic Generation of Antiaromatic Cyclopentadienyl Cations. Journal Of The American Chemical Society, 119 (10) 2371-2375 doi:10.1021/ja962494z
Gassman, Paul G., Doherty, Mark M. (1982) Magnification of neighboring group participation in the solvolytic generation of carbocations through the placement of an electron-withdrawing substituent on the incipient cationic center. Journal Of The American Chemical Society, 104 (13) 3742-3744 doi:10.1021/ja00377a043
Koshy, K. M., Roy, Danielle, Tidwell, Thomas T. (1979) Substituent effects of the trifluoromethyl group on electrophilic additions to alkenes. Solvolysis of the trifluoromethyl group. Protonation of alkenes less basic than ethylene, .rho.+ values of deactivated styrenes, and reactivity-selectivity effects. Journal Of The American Chemical Society, 101 (2) 357-363 doi:10.1021/ja00496a014
 
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