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Klein, Darryl P., Hayes, Jeffrey C., Bergman, Robert G. (1988) Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates. Journal Of The American Chemical Society, 110 (11) 3704-3706 doi:10.1021/ja00219a080

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Reference TypeJournal (article/letter/editorial)
TitleInsertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates
JournalJournal Of The American Chemical Society
AuthorsKlein, Darryl P.Author
Hayes, Jeffrey C.Author
Bergman, Robert G.Author
Year1988 (May)Volume110
Issue11
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00219a080Search in ResearchGate
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Mindat Ref. ID1424257Long-form Identifiermindat:1:5:1424257:3
GUID0
Full ReferenceKlein, Darryl P., Hayes, Jeffrey C., Bergman, Robert G. (1988) Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates. Journal Of The American Chemical Society, 110 (11) 3704-3706 doi:10.1021/ja00219a080
Plain TextKlein, Darryl P., Hayes, Jeffrey C., Bergman, Robert G. (1988) Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates. Journal Of The American Chemical Society, 110 (11) 3704-3706 doi:10.1021/ja00219a080
In(1988, May) Journal Of The American Chemical Society Vol. 110 (11) American Chemical Society (ACS)

See Also

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Stoutland, Page O., Bergman, Robert G. (1988) Carbon-hydrogen insertion and .pi.-complex formation reactions of (.eta.5-C5Me5)(PMe3)Ir with ethylene: an intra- and intermolecular isotope effect study. Journal Of The American Chemical Society, 110 (17) 5732-5744 doi:10.1021/ja00225a025
Klein, Darryl P., Bergman, Robert G. (1989) Synthesis and reactivity of (.eta.5-C5Me5)(PMe3)Ir(CH2): a monomeric (pentamethylcyclopentadienyl)iridium methylene complex. Journal Of The American Chemical Society, 111 (8) 3079-3080 doi:10.1021/ja00190a060
Janowicz, Andrew H., Bergman, Robert G. (1983) Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups. Journal Of The American Chemical Society, 105 (12) 3929-3939 doi:10.1021/ja00350a031
Peterson, Thomas H., Golden, Jeffery T., Bergman, Robert G. (2001) Evidence for the Intervention of Different C−H Activating Intermediates in the Irradiation of (η5-C5Me5)(PMe3)IrH2and the Reaction of (η5-C5Me5)(PMe3)Ir(H)(Cl) with Strong Base. Detection and Spectroscopic Characterization of (η5-C5Me5)(PMe3)Ir(Li)(Cl), an Intermediate in the Dehydrohalogenation Reaction. Journal Of The American Chemical Society, 123 (3) 455-462 doi:10.1021/ja0024993
Chetcuti, Peter A., Hawthorne, M. Frederick (1987) The activation of carbon-hydrogen bonds with intermediates produced by mild thermal and photochemical decomposition of the metallacycle [cyclic] (.eta.5-C5Me5)Ir[C(p-ClC6H4):NOC(:O)](CO) in hydrocarbon solvents. Journal Of The American Chemical Society, 109 (3) 942-943 doi:10.1021/ja00237a074
Burger, Peter, Bergman, Robert G. (1993) Facile intermolecular activation of carbon-hydrogen bonds in methane and other hydrocarbons and silicon-hydrogen bonds in silanes with the iridium(III) complex Cp*(PMe3)Ir(CH3)(OTf) Journal Of The American Chemical Society, 115 (22) 10462-10463 doi:10.1021/ja00075a113
Bengali, A. A., Schultz, Richard H., Moore, C. Bradley, Bergman, Robert G. (1994) Activation of the C-H Bonds in Neopentane and Neopentane-d12 by (.eta.5-C5(CH3)5)Rh(CO)2: Spectroscopic and Temporal Resolution of Rhodium-Krypton and Rhodium-Alkane Complex Intermediates. Journal Of The American Chemical Society, 116 (21) 9585-9589 doi:10.1021/ja00100a024
Moloy, Kenneth G., Marks, Tobin J. (1984) Carbon monoxide activation by organoactinides. A comparative synthetic, thermodynamic, kinetic, and mechanistic investigation of migratory carbon monoxide insertion into actinide-carbon and actinide-hydrogen bonds to yield .eta.2-acyls and .eta.2-formyls. Journal Of The American Chemical Society, 106 (23) 7051-7064 doi:10.1021/ja00335a031
Campion, Brian K., Heyn, Richard H., Tilley, T. Don (1990) A stable .eta.2-silene complex of iridium: (.eta.5-C5Me5)(PMe3)Ir(.eta.2-CH2:SiPh2) Journal Of The American Chemical Society, 112 (10) 4079-4081 doi:10.1021/ja00166a078
Wenzel, Timothy T., Bergman, Robert G. (1986) Inter- and intramolecular insertion of rhenium into carbon-hydrogen bonds. Journal Of The American Chemical Society, 108 (16) 4856-4867 doi:10.1021/ja00276a025
Bottomley, Frank, Magill, C. Philippe, White, Peter S. (1989) Insertion of oxygen into vanadium-carbon bonds. Formation of [(.mu.-.eta.3-C5Me5O3)V(O)]2 from (.eta.-C5Me5)2V and oxygen. Journal Of The American Chemical Society, 111 (8) 3070-3071 doi:10.1021/ja00190a054
 
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