Log InRegister
Quick Links : The Mindat ManualThe Rock H. Currier Digital LibraryMindat Newsletter [Free Download]
Home PageAbout MindatThe Mindat ManualHistory of MindatCopyright StatusWho We AreContact UsAdvertise on Mindat
Donate to MindatCorporate SponsorshipSponsor a PageSponsored PagesMindat AdvertisersAdvertise on Mindat
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe ElementsThe Rock H. Currier Digital LibraryGeologic Time
Minerals by PropertiesMinerals by ChemistryAdvanced Locality SearchRandom MineralRandom LocalitySearch by minIDLocalities Near MeSearch ArticlesSearch GlossaryMore Search Options
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportCoordinate Completion ReportAdd Glossary Item
Mining CompaniesStatisticsUsersMineral MuseumsClubs & OrganizationsMineral Shows & EventsThe Mindat DirectoryDevice SettingsThe Mineral Quiz
Photo SearchPhoto GalleriesSearch by ColorNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day GalleryPhotography

Bianchini, Claudio, Meli, Andrea, Dapporto, Paolo, Tofanari, Anna, Zanello, Piero (1987) Chemical and electrochemical oxidation of the phosphoniodichalcogenoformate complexes (triphos)RhCl(X2CPEt3) (triphos = MeC(CH2PPh2)3; X = S, Se) Synthesis of metal dichalcogenocarbonates from oxygen and phosphonium-betaine-like complexes. X-ray structure of [(triphos)Rh(S2CH(PEt3))](BPh4)2. Inorganic Chemistry, 26 (22) 3677-3682 doi:10.1021/ic00269a013

Advanced
   -   Only viewable:
Reference TypeJournal (article/letter/editorial)
TitleChemical and electrochemical oxidation of the phosphoniodichalcogenoformate complexes (triphos)RhCl(X2CPEt3) (triphos = MeC(CH2PPh2)3; X = S, Se). Synthesis of metal dichalcogenocarbonates from oxygen and phosphonium-betaine-like complexes. X-ray structure of [(triphos)Rh(S2CH(PEt3))](BPh4)2
JournalInorganic Chemistry
AuthorsBianchini, ClaudioAuthor
Meli, AndreaAuthor
Dapporto, PaoloAuthor
Tofanari, AnnaAuthor
Zanello, PieroAuthor
Year1987 (November)Volume26
Issue22
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic00269a013Search in ResearchGate
Generate Citation Formats
Mindat Ref. ID1427237Long-form Identifiermindat:1:5:1427237:0
GUID0
Full ReferenceBianchini, Claudio, Meli, Andrea, Dapporto, Paolo, Tofanari, Anna, Zanello, Piero (1987) Chemical and electrochemical oxidation of the phosphoniodichalcogenoformate complexes (triphos)RhCl(X2CPEt3) (triphos = MeC(CH2PPh2)3; X = S, Se) Synthesis of metal dichalcogenocarbonates from oxygen and phosphonium-betaine-like complexes. X-ray structure of [(triphos)Rh(S2CH(PEt3))](BPh4)2. Inorganic Chemistry, 26 (22) 3677-3682 doi:10.1021/ic00269a013
Plain TextBianchini, Claudio, Meli, Andrea, Dapporto, Paolo, Tofanari, Anna, Zanello, Piero (1987) Chemical and electrochemical oxidation of the phosphoniodichalcogenoformate complexes (triphos)RhCl(X2CPEt3) (triphos = MeC(CH2PPh2)3; X = S, Se) Synthesis of metal dichalcogenocarbonates from oxygen and phosphonium-betaine-like complexes. X-ray structure of [(triphos)Rh(S2CH(PEt3))](BPh4)2. Inorganic Chemistry, 26 (22) 3677-3682 doi:10.1021/ic00269a013
In(1987, November) Inorganic Chemistry Vol. 26 (22) American Chemical Society (ACS)

See Also

These are possibly similar items as determined by title/reference text matching only.

Bianchini, Claudio, Meli, Andrea, Laschi, Franco, Vizza, Francesco, Zanello, Piero (1989) Novel reactions of the [BPh4]- salt of the bifunctional complex [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): one-electron reduction, cleavage of B-H and B-C bonds, and metathesis of CS2-like heteroallene molecules. Inorganic Chemistry, 28 (2) 227-233 doi:10.1021/ic00301a014
Bianchini, Claudio., Meli, Andrea., Orlandini, A. (1982) Chemistry of Et3P.CS2 metal complexes: synthesis of 1,1-dithiolate complexes via nucleophilic attacks on [(triphos)Co(S2CPEt3)](BPh4)2. X-ray structure of [(triphos)Co(S2CO)]. Inorganic Chemistry, 21 (12) 4166-4169 doi:10.1021/ic00142a012
Bianchini, Claudio., Masi, Dante., Meli, Andrea., Sabat, Michal. (1986) Reactions of ethyl cyanoformate with (np3)Ni, (np3)CoH [np3 = N(CH2CH2PPh2)3], and (triphos)Ni [triphos = MeC(CH2PPh2)3]. Crystal structures of the ethoxycarbonyl complexes [(np3)Ni(CO2Et)]BPh4 and (triphos)Ni(CN)(CO2Et). Organometallics, 5. 1670-1675 doi:10.1021/om00139a026
Bianchini, Claudio, Masi, Dante, Mealli, Carlo, Meli, Andrea, Sabat, Michal, Vizza, Francesco (1988) Stepwise metal-assisted conversion of .eta.2-carbon diselenide to .eta.1-phosphoniodiselenoformate, .eta.2-diselenocarbonate, and .eta.2-diselenium. Crystal structure of the rhodium complexes [(triphos)Rh(Se2CO)]BPh4.cntdot.0.5CH2Cl2.cntdot.0.5C4H9OH and [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.cntdot.2DMF [triphos = 1,1,1-tris(diphenyl phosphinomethyl)ethane]. Inorganic Chemistry, 27 (21) 3716-3721 doi:10.1021/ic00294a009
Bianchini, Claudio, Mealli, Carlo, Meli, Andrea, Sabat, Michal (1984) Factors affecting the metal-promoted head-to-head dimerization of carbon disulfide, CS2 to C2S4. Synthesis, chemistry, structure, and MO analysis of [(triphos)Rh(.mu.-C2S4)Rh(triphos)](BPh4)2.CH2Cl2. Inorganic Chemistry, 23 (25) 4125-4127 doi:10.1021/ic00193a003
BIANCHINI, C., MELI, A., ORLANDINI, A. (1983) ChemInform Abstract: CHEMISTRY OF ET3P.CS2 METAL COMPLEXES: SYNTHESIS OF 1,1-DITHIOLATE COMPLEXES VIA NUCLEOPHILIC ATTACKS ON ((TRIPHOS)CO(S2CPET3))(BPH4)2. X-RAY STRUCTURE OF ((TRIPHOS)CO(S2CO)) Chemischer Informationsdienst, 14 (9) doi:10.1002/chin.198309282
Di Vaira, Massimo, Mani, Fabrizio, Moneti, Simonetta, Peruzzini, Maurizio, Sacconi, Luigi, Stoppioni, Piero (1985) Synthesis and characterization of dinuclear metal complexes with the P2S and As2S heteroatomic inorganic rings as bridging units. Crystal and molecular structure of [(triphos)Rh(As2S)Rh(triphos)](BPh4)2.cntdot.2(CH3)2CO [triphos = 1,1,1-tris((diphenylphosphino)methyl)ethane]. Inorganic Chemistry, 24 (14) 2230-2236 doi:10.1021/ic00208a023
Bachechi, F., Bianchini, C., Meli, A. (1993) X-ray structural analyses of copper(I) and silver(I) adducts of the Rh(III) trihydride [(triphos)RhH3], with triphos=CH3C(CH2PPh2)3. Inorganica Chimica Acta, 213 (1). 269-277 doi:10.1016/s0020-1693(00)83837-2
BIANCHINI, C., MEALLI, C., MELI, A., SABAT, M. (1985) ChemInform Abstract: FACTORS AFFECTING THE METAL-PROMOTED HEAD-TO-HEAD DIMERIZATION OF CARBON DISULFIDE, CS2 TO C2S4. SYNTHESIS, CHEMISTRY, STRUCTURE, AND MO ANALYSIS OF ((TRIPHOS)RH(μ-C2S4)RH(TRIPHOS))(BPH4)2.CH2CL2. Chemischer Informationsdienst, 16 (16) doi:10.1002/chin.198516313
Bianchini, Claudio, Mealli, Carlo, Meli, Andrea, Sabat, Michal (1985) Stepwise metal-assisted conversion of carbon diselenide to diselenium and carbon dioxide. Novel bonding mode of the diselenium molecule in the double-Se2-bridged complex [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.2DMF. Journal Of The American Chemical Society, 107 (18) 5317-5318 doi:10.1021/ja00304a072
Allevi, Claudio, Golding, Martin, Heaton, Brian T., Ghilardi, Carlo A., Midollini, Stefano, Orlandini, Annabella (1987) A comparison of face-capping versus fragmentation reactions of [Rh4(CO)12] with triphos, (MeC(CH2PPh2)3) and tripod, (HC(PPh2)3); crystal structure of [(triphos)Rh(μ-CO)2Rh(triphos)]. Journal of Organometallic Chemistry, 326 (1) doi:10.1016/0022-328x(87)80135-3
 
and/or  
Mindat.org is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2025, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph.
To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: August 25, 2025 20:20:40
Go to top of page