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Konno, Takumi, Heeg, Mary Jane, Deutsch, Edward (1988) Thioloato-technetium complexes. 1. Synthesis and characterization of bis(tertiary diphosphine)technetium(III) complexes containing methanethiolato ligands. Single-crystal structural analyses of trans-[TcIII(SCH3)2(DMPE)2]CF3SO3 and trans-[TcIII(SCH3)2(DEPE)2]PF6, where DMPE = 1,2-bis(dimethylphosphino)ethane and DEPE = 1,2-bis(diethylphosphino)ethane. Inorganic Chemistry, 27 (23) 4113-4121 doi:10.1021/ic00296a008

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Reference TypeJournal (article/letter/editorial)
TitleThioloato-technetium complexes. 1. Synthesis and characterization of bis(tertiary diphosphine)technetium(III) complexes containing methanethiolato ligands. Single-crystal structural analyses of trans-[TcIII(SCH3)2(DMPE)2]CF3SO3 and trans-[TcIII(SCH3)2(DEPE)2]PF6, where DMPE = 1,2-bis(dimethylphosphino)ethane and DEPE = 1,2-bis(diethylphosphino)ethane
JournalInorganic Chemistry
AuthorsKonno, TakumiAuthor
Heeg, Mary JaneAuthor
Deutsch, EdwardAuthor
Year1988 (November)Volume27
Issue23
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic00296a008Search in ResearchGate
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Mindat Ref. ID1431450Long-form Identifiermindat:1:5:1431450:6
GUID0
Full ReferenceKonno, Takumi, Heeg, Mary Jane, Deutsch, Edward (1988) Thioloato-technetium complexes. 1. Synthesis and characterization of bis(tertiary diphosphine)technetium(III) complexes containing methanethiolato ligands. Single-crystal structural analyses of trans-[TcIII(SCH3)2(DMPE)2]CF3SO3 and trans-[TcIII(SCH3)2(DEPE)2]PF6, where DMPE = 1,2-bis(dimethylphosphino)ethane and DEPE = 1,2-bis(diethylphosphino)ethane. Inorganic Chemistry, 27 (23) 4113-4121 doi:10.1021/ic00296a008
Plain TextKonno, Takumi, Heeg, Mary Jane, Deutsch, Edward (1988) Thioloato-technetium complexes. 1. Synthesis and characterization of bis(tertiary diphosphine)technetium(III) complexes containing methanethiolato ligands. Single-crystal structural analyses of trans-[TcIII(SCH3)2(DMPE)2]CF3SO3 and trans-[TcIII(SCH3)2(DEPE)2]PF6, where DMPE = 1,2-bis(dimethylphosphino)ethane and DEPE = 1,2-bis(diethylphosphino)ethane. Inorganic Chemistry, 27 (23) 4113-4121 doi:10.1021/ic00296a008
In(1988, November) Inorganic Chemistry Vol. 27 (23) American Chemical Society (ACS)

See Also

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Vanderheyden, Jean Luc, Ketring, Alan R., Libson, Karen, Heeg, Mary Jane, Roecker, Lee, Motz, Philip, Whittle, Robert, Elder, R. C., Deutsch, Edward (1984) Synthesis and characterization of cationic technetium complexes of 1,2-bis(dimethylphosphino)ethane (DMPE) Structure determinations of trans-[TcV(DMPE)2(OH)(O)](F3CSO3)2, trans-[TcIII(DMPE)2Cl2]F3CSO3, and [TcI(DMPE)3]+ using x-ray diffraction, EXAFS, and technetium-99 NMR. Inorganic Chemistry, 23 (20) 3184-3191 doi:10.1021/ic00188a031
Konno, Takumi, Kirchhoff, Jon R., Heineman, William R., Deutsch, Edward (1989) Thiolato-technetium complexes. 2. Synthesis, characterization, electrochemistry, and spectroelectrochemistry of the technetium(III) complexes trans-[Tc(SR)2(DMPE)]+, where R is an alkyl or benzyl group and DMPE is 1,2-bis(dimethylphosphino)ethane. Inorganic Chemistry, 28 (6) 1174-1179 doi:10.1021/ic00305a030
Vanderheyden, Jean Luc, Ketring, Alan R., Libson, Karen, Heeg, Mary Jane, Roecker, Lee, Motz, Philip, Whittle, Robert, Elder, R. C., Deutsch, Edward (1990) Synthesis and characterization of cationic technetium complexes of 1,2-bis(dimethylphosphino)ethane (DMPE) Structure determinations of trans-[TcV(DMPE)2(OH)(O)](F3CSO3)2, trans-[TcIII(DMPE)2Cl2]F3CSO3, and [TcI(DMPE)3]+ using x-ray diffraction, EXAFS, and technetium-99 NMR [Erratum to document cited in CA101(16):142794q]. Inorganic Chemistry, 29 (23) 4840 doi:10.1021/ic00348a052
Konno, Takumi, Heeg, Mary Jane, Deutsch, Edward (1989) Thiolato-technetium complexes. 3. Synthesis and x-ray structural studies on the geometrical isomers cis- and trans-bis(p-chlorobenzenethiolato)bis(1,2-bis(dimethylphosphino)ethane)technetium(II) Inorganic Chemistry, 28 (9) 1694-1700 doi:10.1021/ic00308a020
Konno, Takumi, Heeg, Mary Jane, Stuckey, Jeanne A., Kirchhoff, Jon R., Heineman, William R., Deutsch, Edward (1992) Thiolato-technetium complexes. 5. Synthesis, characterization, and electrochemical properties of bis(o-phenylenebis(dimethylarsine))technetium(II) and -technetium(III) complexes with thiolato ligands. Single-crystal structural analyses of trans-[Tc(SCH3)2(DIARS)2]PF6 and trans-[Tc(SC6H5)2(DIARS)2]0. Inorganic Chemistry, 31 (7) 1173-1181 doi:10.1021/ic00033a011
Vanderheyden, Jean Luc, Heeg, Mary Jane, Deutsch, Edward (1985) Comparison of the chemical and biological properties of trans-[Tc(DMPE)2Cl2]+ and trans-[Re(DMPE)2Cl2]+, where DMPE = 1,2-bis(dimethylphosphino)ethane. Single-crystal structural analysis of trans-[Re(DMPE)2Cl2]PF6. Inorganic Chemistry, 24 (11) 1666-1673 doi:10.1021/ic00205a015
Konno, Takumi, Seeber, Renato, Kirchhoff, Jon R., Heineman, William R., Deutsch, Edward, Heeg, Mary Jane (1993) Thiolato-technetium complexes. 4(1): Synthesis, characterization and electrochemical properties of bis(1,2-bis(dimethylphosphino)-ethane)technetium(III) complexes with arene-thiolato ligands. Transition Metal Chemistry, 18 (2). 209-217 doi:10.1007/bf00139958
VANDERHEYDEN, J.-L., KETRING, A. R., LIBSON, K., HEEG, M. J., ROECKER, L., MOTZ, P., WHITTLE, R., ELDER, R. C., DEUTSCH, E. (1985) ChemInform Abstract: SYNTHESIS AND CHARACTERIZATION OF CATIONIC TECHNETIUM COMPLEXES OF 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE (DMPE) STRUCTURE DETERMINATIONS OF TRANS-(TCV(DMPE)2(OH)(O))(F3CSO3)2, TRANS-(TCIII(DMPE)2CL2)F3CSO3, AND (TCI(DMPE)3)+ USING X-RAY D. Chemischer Informationsdienst, 16 (3) doi:10.1002/chin.198503301
Chang, LihsuehSherry, Deutsch, Edward, Heeg, MaryJane (1993) Synthesis and characterization of the thiolato rhenium(III) complexes cis- and trans-[Re(SC6H4X-p)2(DMPE)2]PF6, X = H, Me or Cl, DMPE = l,2-bis(dimethylphosphino)ethane. Single crystal structural analysis of cis-[Re(SPh)2(DMPE)2]PF6. Transition Metal Chemistry, 18 (3). doi:10.1007/bf00207959
Doyle, Mary Noon, Libson, Karen, Woods, Mary, Sullivan, James C., Deutsch, Edward (1986) Electron-transfer reactions of technetium complexes. 1. Rate of the self-exchange reaction of the technetium(I)/technetium(II) couple [Tc(DMPE)3]+/2+, where DMPE = 1,2-bis(dimethylphosphino)ethane. Inorganic Chemistry, 25 (19) 3367-3371 doi:10.1021/ic00239a011
Roodt, Andreas., Sullivan, James C., Meisel, Dan., Deutsch, Edward. (1991) Electron-transfer reactions of technetium and rhenium complexes. 3. Pulse radiolysis studies on trans-[MIIIX2(DMPE)2]+ and [MI(DMPE)3]+ complexes in aqueous and aqueous surfactant media, where M = Tc or Re, X = Cl or Br, and DMPE = 1,2-bis(dimethylphosphino)ethane. Inorganic Chemistry, 30 (24) 4545-4549 doi:10.1021/ic00024a016
 
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