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Singaram, Bakthan, Goralski, Christian T., Rangaishenvi, Milind V., Brown, Herbert C. (1989) Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either (Z)- or (E)-alkenes. Journal Of The American Chemical Society, 111 (1) 384-386 doi:10.1021/ja00183a068

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Reference TypeJournal (article/letter/editorial)
TitleConvenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either (Z)- or (E)-alkenes
JournalJournal Of The American Chemical Society
AuthorsSingaram, BakthanAuthor
Goralski, Christian T.Author
Rangaishenvi, Milind V.Author
Brown, Herbert C.Author
Year1989 (January)Volume111
Issue1
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00183a068Search in ResearchGate
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Mindat Ref. ID1431683Long-form Identifiermindat:1:5:1431683:2
GUID0
Full ReferenceSingaram, Bakthan, Goralski, Christian T., Rangaishenvi, Milind V., Brown, Herbert C. (1989) Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either (Z)- or (E)-alkenes. Journal Of The American Chemical Society, 111 (1) 384-386 doi:10.1021/ja00183a068
Plain TextSingaram, Bakthan, Goralski, Christian T., Rangaishenvi, Milind V., Brown, Herbert C. (1989) Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either (Z)- or (E)-alkenes. Journal Of The American Chemical Society, 111 (1) 384-386 doi:10.1021/ja00183a068
In(1989, January) Journal Of The American Chemical Society Vol. 111 (1) American Chemical Society (ACS)

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Brown, Herbert C., Dhar, Raj K., Bakshi, Raman K., Pandiarajan, Paul K., Singaram, Bakthan (1989) Major effect of the leaving group in dialkylboron chlorides and triflates in controlling the stereospecific conversion of ketones into either [E]- or [Z]-enol borinates. Journal Of The American Chemical Society, 111 (9) 3441-3442 doi:10.1021/ja00191a058
Brown, Herbert C., Singaram, Bakthan (1984) Hydroboration. 68. Chiral synthesis via organoboranes. 1. A simple procedure to achieve products of essentially 100% optical purity in hydroboration of alkenes with monoisopinocampheylborane. Synthesis of boronic esters and derived products of very high enantiomeric purities. Journal Of The American Chemical Society, 106 (6) 1797-1800 doi:10.1021/ja00318a040
Brown, Herbert, Singaram, Bakthan (1984) Additions and Corrections - Chiral Synthesis via Organoboranes. 1. A Simple Procedure To Acheive Products of Essentially 100% Optical Purity in Hydroboration of Alkenes with Monoisopinocampheylborane. Synthesis of Boronic Esters and Derived Products of Very High Enantiomeric Purities. Journal Of The American Chemical Society, 106 (14) 4069 doi:10.1021/ja00326a600
Brown, Herbert C., Rangaishenvi, Milind V., Jayaraman, Seetharaman (1992) Organoboranes. 54. Exploration of the reactions of (.alpha.-haloallyl)lithium with organoborane derivatives. Simple and convenient procedure for the synthesis of three-carbon homologated boronate esters and terminal alkenes. Organometallics, 11. 1948-1954 doi:10.1021/om00041a029
Brown, Herbert C., Bakshi, Raman K., Singaram, Bakthan. (1988) Chiral synthesis via organoboranes. 12. Conversion of boronic esters of essentially 100% optical purity into monoalkylthexylboranes providing convenient synthetic routes to trans-olefins, cis-olefins, alkynes, and ketones of very high enantiomeric purities. Journal Of The American Chemical Society, 110 (5) 1529-1534 doi:10.1021/ja00213a028
Brown, Herbert C., Zweifel, George (1961) Hydroboration. XI. The Hydroboration of Acetylenes—A Convenient Conversion of Internal Acetylenes into cis-Olefins and of Terminal Acetylenes into Aldehydes. Journal Of The American Chemical Society, 83 (18) 3834-3840 doi:10.1021/ja01479a024
Brown, Herbert C., Joshi, Navalkishore N., Pyun, Chongsuh, Singaram, Bakthan (1989) Chiral synthesis via organoboranes. 20. Conversion of boronic esters of essentially 100% optical purity to B-alkyl-9-borabicyclo[3.3.1]nonanes of very high optical purity. Synthesis of optically active homologated esters, nitriles, and ketones. Journal Of The American Chemical Society, 111 (5) 1754-1758 doi:10.1021/ja00187a030
Brown, Herbert C., Ravindran, N. (1976) Hydroboration. XLI. Hydroboration of alkenes and alkynes with dichloroborane etherates. Convenient procedures for the preparation of alkyl- and alkenyldichloroboranes and their derivatives. Journal Of The American Chemical Society, 98 (7) 1798-1806 doi:10.1021/ja00423a026
Brown, Herbert C., Imai, Toshiro, Desai, Manoj C., Singaram, Bakthan (1985) Chiral synthesis via organoboranes. 3. Conversion of boronic esters of essentially 100% optical purity to aldehydes, acids, and homologated alcohols of very high enantiomeric purities. Journal Of The American Chemical Society, 107 (17) 4980-4983 doi:10.1021/ja00303a026
Brown, Herbert C., Ravindran, N. (1976) Hydroboration. XL. Hydroboration of alkenes and alkynes with monochloroborane etherates. Convenient procedures for the preparation of dialkyl-, monoalkyl-, and dialkenylchloroboranes and their derivatives. Journal Of The American Chemical Society, 98 (7) 1785-1798 doi:10.1021/ja00423a025
Brown, Herbert C., Gupta, S. K. (1975) Hydroboration. XXXIX. 1,3,2-Benzodioxaborole (catecholborane) as a new hydroboration reagent for alkenes and alkynes. General synthesis of alkane- and alkeneboronic acids and esters via hydroboration. Directive effects in the hydroboration of alkenes and alkynes with catecholborane. Journal Of The American Chemical Society, 97 (18) 5249-5255 doi:10.1021/ja00851a038
 
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