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Mura, Pasquale, Segre, Annalaura, Sostero, Silvana (1989) Stable paramagnetic dihydrido complexes of iridium(IV): synthesis, x-ray crystal structure, and behavior in solution of IrIV(H)2(Cl)2(P-iso-Pr3)2 (1) and IrIV(H)2(Cl)2(PCy3)2 (2) Inorganic Chemistry, 28 (14) 2853-2858 doi:10.1021/ic00313a031

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Reference TypeJournal (article/letter/editorial)
TitleStable paramagnetic dihydrido complexes of iridium(IV): synthesis, x-ray crystal structure, and behavior in solution of IrIV(H)2(Cl)2(P-iso-Pr3)2 (1) and IrIV(H)2(Cl)2(PCy3)2 (2)
JournalInorganic Chemistry
AuthorsMura, PasqualeAuthor
Segre, AnnalauraAuthor
Sostero, SilvanaAuthor
Year1989 (July)Volume28
Issue14
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic00313a031Search in ResearchGate
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Mindat Ref. ID1434304Long-form Identifiermindat:1:5:1434304:9
GUID0
Full ReferenceMura, Pasquale, Segre, Annalaura, Sostero, Silvana (1989) Stable paramagnetic dihydrido complexes of iridium(IV): synthesis, x-ray crystal structure, and behavior in solution of IrIV(H)2(Cl)2(P-iso-Pr3)2 (1) and IrIV(H)2(Cl)2(PCy3)2 (2) Inorganic Chemistry, 28 (14) 2853-2858 doi:10.1021/ic00313a031
Plain TextMura, Pasquale, Segre, Annalaura, Sostero, Silvana (1989) Stable paramagnetic dihydrido complexes of iridium(IV): synthesis, x-ray crystal structure, and behavior in solution of IrIV(H)2(Cl)2(P-iso-Pr3)2 (1) and IrIV(H)2(Cl)2(PCy3)2 (2) Inorganic Chemistry, 28 (14) 2853-2858 doi:10.1021/ic00313a031
In(1989, July) Inorganic Chemistry Vol. 28 (14) American Chemical Society (ACS)

See Also

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Mura, Pasquale. (1986) Synthesis and x-ray crystal structure of the stable paramagnetic iridium dihydrido complex Ir(H)2(Cl)2(P-iso-Pr3)2. Journal Of The American Chemical Society, 108 (2) 351-352 doi:10.1021/ja00262a058
MURA, P. (1986) ChemInform Abstract: Synthesis and X-Ray Crystal Structure of the Stable Paramagnetic Dihydrido Complex Ir(H)2(Cl)2(P-iPr3)2. Chemischer Informationsdienst, 17 (20) doi:10.1002/chin.198620298
Capitani, D., Mura, P., Ajò, D. (1993) Crystal and molecular structure of [Ir(H)x(Cl)3(PiPr3)2],1(x= 1 or 2): another example of IrIVparamagnetic hydride or an iridium(V) complex, transient intermediate of [IrIV(H)2(Cl)2(PiPr3)2],2?. Acta Crystallographica Section A Foundations of Crystallography, 49. doi:10.1107/s0108767378093320
MURA, P., SEGRE, A. (1986) ChemInform Abstract: Unusual Behavior of the Stable Paramagnetic Dihydridoiridium(IV) Complex Ir(H)2(Cl)2(iPr3P)2 in Solution. Chemischer Informationsdienst, 17 (36) doi:10.1002/chin.198636286
Capitani, Donatella, Mura, Pasquale (1997) Do paramagnetic platinum metal hydrides really exist? A reinvestigation of the synthesis and magnetochemical properties of Ir(H)x(Cl)2(P-i-Pr3)2 (1). Syntheses and crystal structure determinations of trans-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (2), cis-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (4) and trans-Ir(Cl)(CO)(P-i-Pr3)2 (5). Inorganica Chimica Acta, 258 (2). 169-181 doi:10.1016/s0020-1693(96)05498-9
Mura, Pasquale, Segre, Annalaura (1986) Ungewöhnliches Verhalten des stabilen paramagnetischen Dihydridoiridium(IV)-Komplexes [Ir(H)2(Cl)2(iPr3P)2] in Lösung. Angewandte Chemie, 98 (5). 453-454 doi:10.1002/ange.19860980516
Albinati, Alberto, Lehner, Hans, Venanzi, Luigi M. (1985) Some new rhodium(I)-iridium(III) complexes with bridging hydride and chloride ligands. Synthesis of compounds [L2Rh(.mu.-H)(.mu.-Cl)IrH2L'2] (L = PEt3 or L2 = diphos; L' = PEt3, P-iso-Pr3) and the x-ray crystal structure of [(PEt3)2Rh(.mu.-H)(.mu.-Cl)IrH2(PEt3)2]. Inorganic Chemistry, 24 (10) 1483-1488 doi:10.1021/ic00204a016
Allevi, Moira, Capitani, Donatella, Ettorre, Alessandro, Mura, Pasquale (1998) Syntheses, spectroscopic characterization and X-ray crystal structures of [HP-i-Pr3]2[IrCl6] (1), [HP-i-Pr3]2[Ir2Cl8(P-i-Pr3)] (2) and [HP-i-Pr3] [Ir2Cl7(P-i-Pr3)2] (3): three possible precursors of the complex Ir(H) (Cl)2(P-i-Pr3)2 (4). Inorganica Chimica Acta, 282 (1). 17-24 doi:10.1016/s0020-1693(98)00192-3
Ajò, D., Attanasio, D., Lucente, S., Mura, P., Segre, A.L., De Zuane, F. (1992) The unusual paramagnetic behaviour of IrIV and RhIV dihydrido complexes in the solid state and in solution. Journal of Magnetism and Magnetic Materials, 104. 1997-1998 doi:10.1016/0304-8853(92)91639-b
Gusev, D. G., Vymenits, A. B., Bakhmutov, V. I. (1992) Reactions of carbonylchlorohydridobis(triisopropylphosphine)ruthenium with molecular hydrogen in solution. New molecular hydrogen complexes of ruthenium: RuH(H2)Cl(CO)[P(iso-Pr)3]2 and Ru(H)2(H2)(CO)[P(iso-Pr)3]2. Inorganic Chemistry, 31 (1) 1-2 doi:10.1021/ic00027a001
Wilcox, Bruce E., Ho, Douglas M., Deutsch, Edward (1989) Synthesis and characterization of technetium(III) complexes containing 2,2'-bipyridine and 1,10-phenanthroline. X-ray crystal structures of cis(Cl),trans(P)-[TcCl2(P(CH3)2C6H5)2(bpy)]B(C6H5)4, cis(Cl),trans(P)-[TcCl2(P(CH3)2C6H5)2(phen)]B(C6H5)4, and cis(Cl),trans(P)-[TcCl2(P(CH3CH2)(C6H5)2)2(bpy)]SO3CF3. Inorganic Chemistry, 28 (9) 1743-1751 doi:10.1021/ic00308a029
 
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