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Brown, R. S., Slebocka-Tilk, H., Bennet, A. J., Bellucci, G., Bianchini, R., Ambrosetti, R. (1990) Investigation of the early stages of electrophilic addition of bromine to olefins. Kinetic evidence for a reversibly formed bromonium ion in the reaction of bromine with tetraisobutylethylene. Journal Of The American Chemical Society, 112 (17) 6310-6316 doi:10.1021/ja00173a019

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Reference TypeJournal (article/letter/editorial)
TitleInvestigation of the early stages of electrophilic addition of bromine to olefins. Kinetic evidence for a reversibly formed bromonium ion in the reaction of bromine with tetraisobutylethylene
JournalJournal Of The American Chemical Society
AuthorsBrown, R. S.Author
Slebocka-Tilk, H.Author
Bennet, A. J.Author
Bellucci, G.Author
Bianchini, R.Author
Ambrosetti, R.Author
Year1990 (August)Volume112
Issue17
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00173a019Search in ResearchGate
Generate Citation Formats
Mindat Ref. ID1442367Long-form Identifiermindat:1:5:1442367:3
GUID0
Full ReferenceBrown, R. S., Slebocka-Tilk, H., Bennet, A. J., Bellucci, G., Bianchini, R., Ambrosetti, R. (1990) Investigation of the early stages of electrophilic addition of bromine to olefins. Kinetic evidence for a reversibly formed bromonium ion in the reaction of bromine with tetraisobutylethylene. Journal Of The American Chemical Society, 112 (17) 6310-6316 doi:10.1021/ja00173a019
Plain TextBrown, R. S., Slebocka-Tilk, H., Bennet, A. J., Bellucci, G., Bianchini, R., Ambrosetti, R. (1990) Investigation of the early stages of electrophilic addition of bromine to olefins. Kinetic evidence for a reversibly formed bromonium ion in the reaction of bromine with tetraisobutylethylene. Journal Of The American Chemical Society, 112 (17) 6310-6316 doi:10.1021/ja00173a019
In(1990, August) Journal Of The American Chemical Society Vol. 112 (17) American Chemical Society (ACS)

See Also

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Gedye, R., Brown, R. S., Slebocka-Tilk, H., Buschek, J. M., Kopecky, K. R. (1984) The question of reversible formation of bromonium ions during the course of electrophilic bromination of olefins. 1. Formal transfer of bromine(1+) ion to scavenger olefins from the solvolytically generated bromonium ions of cyclohexene and cyclopentene. Journal Of The American Chemical Society, 106 (16) 4515-4521 doi:10.1021/ja00328a035
Bennet, A. J., Brown, R. S., McClung, R. E. D., Klobukowski, M., Aarts, G. H. M., Santarsiero, B. D., Bellucci, Giuseppe, Bianchini, Roberto (1991) An unprecedented rapid and direct bromine(1+) ion transfer from the bromonium ion of adamantylideneadamantane to acceptor olefins. Journal Of The American Chemical Society, 113 (22) 8532-8534 doi:10.1021/ja00022a057
Bennet, A. J., Slebocka-Tilk, H., Brown, R. S., Guthrie, J. Peter, Jodhan, A. (1990) Concurrent oxygen-18 exchange accompanying the acid-catalyzed hydrolysis of anilides. Implications for the lifetimes of reversibly formed intermediates. Journal Of The American Chemical Society, 112 (23) 8497-8506 doi:10.1021/ja00179a039
Nagorski, R. W., Brown, R. S. (1992) Electrophilic addition of bromine to olefins in the presence of nucleophilic trapping anions. Implications for the lifetimes of bromonium ion intermediates produced from electrophilic bromination of olefins in methanol. Journal Of The American Chemical Society, 114 (20) 7773-7779 doi:10.1021/ja00046a024
Bellucci, Giuseppe, Bianchini, Roberto, Chiappe, Cinzia, Marioni, Franco, Ambrosetti, Roberto, Brown, Robert Stanley, Slebocka-Tilk, Henryka (1989) The solution behavior of the adamantylideneadamantane-bromine system: existence of equilibrium mixtures of bromonium-polybromide salts and a strong 1:1 molecular charge-transfer complex. Journal Of The American Chemical Society, 111 (7) 2640-2647 doi:10.1021/ja00189a044
Slebocka-Tilk, H., Ball, R. G., Brown, R. Stan (1985) The question of reversible formation of bromonium ions during the course of electrophilic bromination of olefins. 2. The crystal and molecular structure of the bromonium ion of adamantylideneadamantane. Journal Of The American Chemical Society, 107 (15) 4504-4508 doi:10.1021/ja00301a021
Nagorski, R. W., Slebocka-Tilk, H., Brown, R. S. (1994) Observation of an unusually large inverse secondary deuterium kinetic isotope effect for the reaction of a sterically congested olefin with bromine. Journal Of The American Chemical Society, 116 (1) 419-420 doi:10.1021/ja00080a067
Bellucci, Giuseppe, Bianchini, Roberto, Chiappe, Cinzia, Brown, Robert Stanley, Slebocka-Tilk, Henryka (1991) Different reversibility of bromonium vs .beta.-bromocarbonium ions formed during the electrophilic bromination of substituted stilbenes. Evidence for rate determination during the product-forming step. Journal Of The American Chemical Society, 113 (21) 8012-8016 doi:10.1021/ja00021a030
BELLUCCI, G., BIANCHINI, R., AMBROSETTI, R. (1985) ChemInform Abstract: DIRECT EVIDENCE FOR BROMINE-OLEFIN CHARGE-TRANSFER COMPLEXES AS ESSENTIAL INTERMEDIATES OF THE FAST IONIC ADDITION OF BROMINE TO CYCLOHEXENE. Chemischer Informationsdienst, 16 (34) doi:10.1002/chin.198534138
SLEBOCKA-TILK, H., BALL, R. G., BROWN, R. S. (1985) ChemInform Abstract: THE QUESTION OF REVERSIBLE FORMATION OF BROMONIUM IONS DURING THE COURSE OF ELECTROPHILIC BROMINATION OF OLEFINS. 2. THE CRYSTAL AND MOLECULAR STRUCTURE OF THE BROMONIUM ION OF ADAMANTYLIDENEADAMANTANE. Chemischer Informationsdienst, 16 (45) doi:10.1002/chin.198545052
Bellucci, Giuseppe, Bianchini, Roberto, Ambrosetti, Roberto (1985) Direct evidence for bromine-olefin charge-transfer complexes as essential intermediates of the fast ionic addition of bromine to cyclohexene. Journal Of The American Chemical Society, 107 (8) 2464-2471 doi:10.1021/ja00294a044
 
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