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Parkin, Gerard, Van Asselt, Allan, Leahy, David J., Whinnery, LeRoy, Hua, Nhi G., Quan, Roger W., Henling, Lawrence M., Schaefer, William P., Santarsiero, Bernard D., Bercaw, John E. (1992) Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?. Inorganic Chemistry, 31 (1) 82-85 doi:10.1021/ic00027a016

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Reference TypeJournal (article/letter/editorial)
TitleOxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?
JournalInorganic Chemistry
AuthorsParkin, GerardAuthor
Van Asselt, AllanAuthor
Leahy, David J.Author
Whinnery, LeRoyAuthor
Hua, Nhi G.Author
Quan, Roger W.Author
Henling, Lawrence M.Author
Schaefer, William P.Author
Santarsiero, Bernard D.Author
Bercaw, John E.Author
Year1992 (January)Volume31
Issue1
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic00027a016Search in ResearchGate
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Mindat Ref. ID1446593Long-form Identifiermindat:1:5:1446593:4
GUID0
Full ReferenceParkin, Gerard, Van Asselt, Allan, Leahy, David J., Whinnery, LeRoy, Hua, Nhi G., Quan, Roger W., Henling, Lawrence M., Schaefer, William P., Santarsiero, Bernard D., Bercaw, John E. (1992) Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?. Inorganic Chemistry, 31 (1) 82-85 doi:10.1021/ic00027a016
Plain TextParkin, Gerard, Van Asselt, Allan, Leahy, David J., Whinnery, LeRoy, Hua, Nhi G., Quan, Roger W., Henling, Lawrence M., Schaefer, William P., Santarsiero, Bernard D., Bercaw, John E. (1992) Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?. Inorganic Chemistry, 31 (1) 82-85 doi:10.1021/ic00027a016
In(1992, January) Inorganic Chemistry Vol. 31 (1) American Chemical Society (ACS)

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Van Asselt, Allan., Trimmer, Mark S., Henling, Larry M., Bercaw, John E. (1988) Dioxygen-derived peroxo-alkyl complexes of permethyltantalocene. Structural characterization of (.eta.5-C5Me5)2Ta(.eta.2-O2)(CH2C6H5) and acid-catalyzed rearrangement to oxo-alkoxide derivatives. Journal Of The American Chemical Society, 110 (24) 8254-8255 doi:10.1021/ja00232a058
Whinnery, LeRoy L., Henling, Lawrence M., Bercaw, John E. (1991) Synthesis and structure of moderately stable metallaoxetanes: [cyclic](.eta.5-C5Me5)2(CH3)TaOCHRCH2 (R = H, C6H5) Investigations of their decomposition to olefin and (.eta.5-C5Me5)2Ta(:O)CH3 and evidence revealing that they are not intermediates in the deoxygenation of epoxides by [(.eta.5-C5Me5)2Ta(CH3)]. Journal Of The American Chemical Society, 113 (20) 7575-7582 doi:10.1021/ja00020a019
McDade, Christine., Gibson, Vernon C., Santarsiero, Bernard D., Bercaw, John E. (1988) Interaction of trialkylaluminum reagents with metal-bound ethylene and carbon monoxide. The molecular structure of (.eta.5-C5Me5)2Ta(H)(C2H4.cntdot.AlEt3). Organometallics, 7. 1-7 doi:10.1021/om00091a001
Van Asselt, Allan., Santarsiero, Bernard D., Bercaw, John E. (1986) The tert-butyl peroxide complexes of permethylhafnocene, (.eta.5-C5Me5)2Hf(R)(OOCMe3) Stoichiometric transformation of alkyl tert-butyl peroxide derivatives to alkoxy tert-butoxides, (.eta.5-C5Me5)2Hf(OR)(OCMe3) Journal Of The American Chemical Society, 108 (26) 8291-8293 doi:10.1021/ja00286a044
Parkin, Gerard, Marsh, Richard E., Schaefer, William P., Bercaw, John E. (1988) Structure of (pentamethylcyclopentadienyl)((pentamethylcyclopentadienyl)oxy)dioxotungsten(VI), (.eta.5-C5Me5)W(O)2(OC5Me5) Structural evidence for the strong trans influence of the oxo ligand. Inorganic Chemistry, 27 (18) 3262-3264 doi:10.1021/ic00291a052
Joergensen, Karl Anker (1993) MO explanation of the "unexpected" structure of (.eta.5-C5Me5)2Ta(:NC6H5)H. Inorganic Chemistry, 32 (8) 1521-1522 doi:10.1021/ic00060a032
Shapiro, Pamela J., Henling, Lawrence M., Marsh, Richard E., Bercaw, John E. (1990) Hydrazido(1-) and 2,2-dimethylhydrazido(1-) derivatives of permethylscandocene. Preparation and structural characterization of their products from reactions with acetonitrile: (.eta.5-C5Me5)2ScN(H)C(CH3)NNH2 and (.eta.5-C5Me5)2ScN(H)C(CH3)NNMe2. Inorganic Chemistry, 29 (22) 4560-4565 doi:10.1021/ic00347a045
Van Asselt, Allan., Burger, Barbara J., Gibson, Vernon C., Bercaw, John E. (1986) Hydrido methylidene, hydrido vinylidene, hydrido oxo, and hydrido formaldehyde derivatives of bis(pentamethylcyclopentadienyl)tantalum. Journal Of The American Chemical Society, 108 (17) 5347-5349 doi:10.1021/ja00277a051
St. Clair, Martin., Schaefer, William P., Bercaw, John E. (1991) Reactivity of permethylscandocene derivatives with acetylene. Structure of acetylenediylbis(permethylscandocene), (.eta.5-C5Me5)2ScC.tplbond.CSc(.eta.5-C5Me5)2. Organometallics, 10. 525-527 doi:10.1021/om00049a001
Bulls, A. Ray., Schaefer, William P., Serfas, Michael., Bercaw, John E. (1987) Intramolecular carbon-hydrogen bond activation of benzyl ligands by metalated cyclopentadienyl derivatives of permethylhafnocene. Molecular structure of (.eta.5-C5Me5)(.eta.5,.eta.1-C5Me4CH2)HfCH2C6H5 and the mechanism of rearrangement to its hafnabenzocyclobutene tautomer [cyclic] (.eta.5-C5Me5)2Hf(o-CH2C6H4). Organometallics, 6. 1219-1226 doi:10.1021/om00149a016
VAN ASSELT, A., BURGER, B. J., GIBSON, V. C., BERCAW, J. E. (1986) ChemInform Abstract: Hydrido Methylidene, Hydrido Vinylidene, Hydrido Oxo, and Hydrido Formaldehyde Derivatives of Bis(pentamethylcyclopentadienyl)tantalum. Chemischer Informationsdienst, 17 (52) doi:10.1002/chin.198652235
 
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