Reference Type | Journal (article/letter/editorial) |
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Title | Structural behaviour of chkalovite, Na2BeSi2O6: a member of the cristobalite family |
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Journal | Mineralogical Magazine | ISSN | 0026-461X |
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Authors | Henderson, C.M.B. | Author |
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Taylor, D. | Author |
Year | 1989 (March) | Volume | 53 |
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Issue | 369 |
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Publisher | Mineralogical Society |
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Download URL | https://rruff.info/doclib/MinMag/Volume_53/53-369-117.pdf+ |
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DOI | doi:10.1180/minmag.1989.053.369.14Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 1481 | Long-form Identifier | mindat:1:5:1481:0 |
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GUID | 0 |
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Full Reference | Henderson, C.M.B., Taylor, D. (1989) Structural behaviour of chkalovite, Na2BeSi2O6: a member of the cristobalite family. Mineralogical Magazine, 53 (369) 117-119 doi:10.1180/minmag.1989.053.369.14 |
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Plain Text | Henderson, C.M.B., Taylor, D. (1989) Structural behaviour of chkalovite, Na2BeSi2O6: a member of the cristobalite family. Mineralogical Magazine, 53 (369) 117-119 doi:10.1180/minmag.1989.053.369.14 |
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In | (1989, March) Mineralogical Magazine Vol. 53 (369) Mineralogical Society |
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Abstract/Notes | The atomic structure of chkalovite, Na2BeSi2O6, has been determined and refined by Simonov et al. (1976). It is orthorhombic, space group Fdd2, with cell parameters: a = 21.129 (5), b = 6.881 (2), and c = 21.188 (5)/Ã…. The structure is very similar to that of alpha-cristobalite (Dollase, 1965), comprising a framework of ordered BeO4 and SiO4 tetrahedra with the sodium atoms occupying sites within the cavities of the beryllosilicate framework. Taylor (1972) developed a tilting model for the cristobalite structure assuming regular tetrahedra. In addition to the single tilt system deduced for cristobalite (Taylor, 1972, 1984a) chkalovite has secondary tilt systems involving a slight adjustment of the structure by a small cooperative tilt or twist of some tetrahedra about one or more of their three-fold axes (see fig. 1 of Simonov et al., 1976). |
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