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Engelbrecht, Leon, Murray, Pieter, Koch, Klaus R. (2015) Isotope Effects in 195Pt NMR Spectroscopy: Unique 35/37Cl- and 16/18O-Resolved “Fingerprints” for All [PtCl6–n(OH)n]2– (n = 1–5) Anions in an Alkaline Solution and the Implications of the Trans Influence. Inorganic Chemistry, 54 (6) 2752-2764 doi:10.1021/ic502901d

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Reference TypeJournal (article/letter/editorial)
TitleIsotope Effects in 195Pt NMR Spectroscopy: Unique 35/37Cl- and 16/18O-Resolved “Fingerprints” for All [PtCl6–n(OH)n]2– (n = 1–5) Anions in an Alkaline Solution and the Implications of the Trans Influence
JournalInorganic Chemistry
AuthorsEngelbrecht, LeonAuthor
Murray, PieterAuthor
Koch, Klaus R.Author
Year2015 (March 16)Volume54
Issue6
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic502901dSearch in ResearchGate
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Mindat Ref. ID1609957Long-form Identifiermindat:1:5:1609957:7
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Full ReferenceEngelbrecht, Leon, Murray, Pieter, Koch, Klaus R. (2015) Isotope Effects in 195Pt NMR Spectroscopy: Unique 35/37Cl- and 16/18O-Resolved “Fingerprints” for All [PtCl6–n(OH)n]2– (n = 1–5) Anions in an Alkaline Solution and the Implications of the Trans Influence. Inorganic Chemistry, 54 (6) 2752-2764 doi:10.1021/ic502901d
Plain TextEngelbrecht, Leon, Murray, Pieter, Koch, Klaus R. (2015) Isotope Effects in 195Pt NMR Spectroscopy: Unique 35/37Cl- and 16/18O-Resolved “Fingerprints” for All [PtCl6–n(OH)n]2– (n = 1–5) Anions in an Alkaline Solution and the Implications of the Trans Influence. Inorganic Chemistry, 54 (6) 2752-2764 doi:10.1021/ic502901d
In(2015, March) Inorganic Chemistry Vol. 54 (6) American Chemical Society (ACS)

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Murray, Pieter, Gerber, Wilhelmus J., Koch, Klaus R. (2012) 35/37Cl and 16/18O isotope resolved 195Pt NMR: unique spectroscopic ‘fingerprints’ for unambiguous speciation of [PtCln(H2O)6−n]4−n (n = 2–5) complexes in an acidic aqueous solution. Dalton Transactions, 41 (35). 10533pp. doi:10.1039/c2dt31201h
Engelbrecht, Leon, Mocci, Francesca, Laaksonen, Aatto, Koch, Klaus R. (2018) 195Pt NMR and Molecular Dynamics Simulation Study of the Solvation of [PtCl6]2– in Water–Methanol and Water–Dimethoxyethane Binary Mixtures. Inorganic Chemistry, 57 (19) 12025-12037 doi:10.1021/acs.inorgchem.8b01554
van Wyk, Pieter-Hugo, Gerber, Wilhelmus J., Koch, Klaus R. (2011) A robust method for speciation, separation and photometric characterization of all [PtCl6−nBrn]2− (n=0–6) and [PtCl4−nBrn]2− (n=0–4) complex anions by means of ion-pairing RP-HPLC coupled to ICP-MS/OES, validated by high resolution 195Pt NMR spectroscopy. Analytica Chimica Acta, 704 (1). 154-161 doi:10.1016/j.aca.2011.07.037
Geswindt, Theodor E., Gerber, Wilhelmus J., Brand, D. Jacobus, Koch, Klaus R. (2012) 35Cl/37Cl isotope effects in 103Rh NMR of [RhCln(H2O)6−n]3−n complex anions in hydrochloric acid solution as a unique ‘NMR finger-print’ for unambiguous speciation. Analytica Chimica Acta, 730. 93-98 doi:10.1016/j.aca.2012.02.009
Koch, Klaus R., Engelbrecht, Leon (2017) Intrinsic37/35Cl and18/16O isotope shifts in195Pt and103Rh NMR of purely inorganic Pt and Rh complexes as unique spectroscopic fingerprints for unambiguous assignment of structure. Dalton Transactions, 46 (29). 9303-9315 doi:10.1039/c7dt01722g
Irving, Anne, Koch, Klaus R., Matoetoe, M. (1993) Deceptively simple Pt complexes of N, N-dialkyl-N′-benzoylthiourea: a 1H, 13C and 195Pt NMR study of their acid-base chemistry in solution and the molecular structure of cis-bis(N, N′-di(n-butyl)-N′-benzoylthioureato)platinum(II). Inorganica Chimica Acta, 206 (2). 193-199 doi:10.1016/s0020-1693(00)82866-2
van Wyk, Pieter-Hugo, Gerber, Wilhelmus J., Koch, Klaus R. (2012) Direct determination of metal to halide mole ratios in platinum complex anions [PtCl6−nBrn]2− (n = 0–6) by means of HPLC-ICP-OES using Cl, Br and Pt emissions of all separated species. Journal of Analytical Atomic Spectrometry, 27 (4). 577pp. doi:10.1039/c2ja10342g
Davis, John C., Bühl, Michael, Koch, Klaus R. (2013) Probing Isotope Shifts in 103Rh and 195Pt NMR Spectra with Density Functional Theory. The Journal of Physical Chemistry A, 117 (33). 8054-8064 doi:10.1021/jp405453c
Remsing, Richard C., Wildin, Jayme L., Rapp, Ashleigh L., Moyna, Guillermo (2007) Hydrogen Bonds in Ionic Liquids Revisited: 35/37Cl NMR Studies of Deuterium Isotope Effects in 1-n-Butyl-3-Methylimidazolium Chloride. The Journal of Physical Chemistry B, 111 (40). 11619-11621 doi:10.1021/jp0756449
Nkabyo, Henry A., Procacci, Barbara, Duckett, Simon B., Koch, Klaus R. (2019) Reversible photo-isomerization of cis-[Pd(L-κS,O)2] (HL = N,N-diethyl-N′-1-naphthoylthiourea) to trans-[Pd(L-κS,O)2] and the unprecedented formation of trans-[Pd(L-κS,N)2] in solution. Dalton Transactions, 48 (46). 17241-17251 doi:10.1039/c9dt03672e
Mueller, Horst, Obergfell, P. (1994) Chemical effects of the chlorine 37Cl(n,.gamma.)38Cl nuclear reaction in mixed potassium cis/trans- and fac/mer-hexa(chloro/fluoro)osmates(IV), K2OsClnF6-n (n = 2-4). The Journal of Physical Chemistry, 98 (1). 193-198 doi:10.1021/j100052a032
 
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