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Böttcher, Michael E., Gehlken, Peer-Lennart, Skogby, Henrik, Reutel, Christian (1997) The vibrational spectra of BaMg(CO3)2 (norsethite) Mineralogical Magazine, 61 (405) 249-256 doi:10.1180/minmag.1997.061.405.08

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Reference TypeJournal (article/letter/editorial)
TitleThe vibrational spectra of BaMg(CO3)2 (norsethite)
JournalMineralogical MagazineISSN0026-461X
AuthorsBöttcher, Michael E.Author
Gehlken, Peer-LennartAuthor
Skogby, HenrikAuthor
Reutel, ChristianAuthor
Year1997 (April)Volume61
Issue405
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_61/61-405-249.pdf+
DOIdoi:10.1180/minmag.1997.061.405.08Search in ResearchGate
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Mindat Ref. ID162Long-form Identifiermindat:1:5:162:3
GUID0
Full ReferenceBöttcher, Michael E., Gehlken, Peer-Lennart, Skogby, Henrik, Reutel, Christian (1997) The vibrational spectra of BaMg(CO3)2 (norsethite) Mineralogical Magazine, 61 (405) 249-256 doi:10.1180/minmag.1997.061.405.08
Plain TextBöttcher, Michael E., Gehlken, Peer-Lennart, Skogby, Henrik, Reutel, Christian (1997) The vibrational spectra of BaMg(CO3)2 (norsethite) Mineralogical Magazine, 61 (405) 249-256 doi:10.1180/minmag.1997.061.405.08
In(1997, April) Mineralogical Magazine Vol. 61 (405) Mineralogical Society
Abstract/NotesAbstractThe FTIR spectra of synthetic BaMg(CO3)2 (norsethite) are measured at ambient temperature and atmospheric pressure, and the influence of formation conditions on the FTIR spectra is investigated. The results are compared with those for natural norsethite from Långban (Sweden) and Rosh Pinah (Namibia). The Raman spectrum of synthetic norsethite is reported, too. A number of first-order internal modes of the carbonate ion group (ν1, ν2, ν3, ν4) are found to be infrared and Raman active. Additonally, the (ν1+ν3) and (ν1+ν4) combination modes and the (2*ν2) overtone are observed in the FTIR and Raman spectrum, respectively. The carbon isotopic-shift coefficient for ν2 due to the substitution of 12C by 13C (ν2(13CO32-)/ν2(12CO32-) = 0.971 ± 0.002), observed by FTIR spectroscopy, agrees with the theoretical value of 0.969.

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Norsethite


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