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Stubbert, Bryan D., Marks, Tobin J. (2007) Mechanistic Investigation of Intramolecular Aminoalkene and Aminoalkyne Hydroamination/Cyclization Catalyzed by Highly Electrophilic, Tetravalent Constrained Geometry 4d and 5f Complexes. Evidence for an M−N σ-Bonded Insertive Pathway. Journal Of The American Chemical Society, 129 (19) 6149-6167 doi:10.1021/ja0675898

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Reference TypeJournal (article/letter/editorial)
TitleMechanistic Investigation of Intramolecular Aminoalkene and Aminoalkyne Hydroamination/Cyclization Catalyzed by Highly Electrophilic, Tetravalent Constrained Geometry 4d and 5f Complexes. Evidence for an M−N σ-Bonded Insertive Pathway
JournalJournal Of The American Chemical Society
AuthorsStubbert, Bryan D.Author
Marks, Tobin J.Author
Year2007 (May)Volume129
Issue19
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja0675898Search in ResearchGate
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Mindat Ref. ID1682837Long-form Identifiermindat:1:5:1682837:7
GUID0
Full ReferenceStubbert, Bryan D., Marks, Tobin J. (2007) Mechanistic Investigation of Intramolecular Aminoalkene and Aminoalkyne Hydroamination/Cyclization Catalyzed by Highly Electrophilic, Tetravalent Constrained Geometry 4d and 5f Complexes. Evidence for an M−N σ-Bonded Insertive Pathway. Journal Of The American Chemical Society, 129 (19) 6149-6167 doi:10.1021/ja0675898
Plain TextStubbert, Bryan D., Marks, Tobin J. (2007) Mechanistic Investigation of Intramolecular Aminoalkene and Aminoalkyne Hydroamination/Cyclization Catalyzed by Highly Electrophilic, Tetravalent Constrained Geometry 4d and 5f Complexes. Evidence for an M−N σ-Bonded Insertive Pathway. Journal Of The American Chemical Society, 129 (19) 6149-6167 doi:10.1021/ja0675898
In(2007, May) Journal Of The American Chemical Society Vol. 129 (19) American Chemical Society (ACS)

See Also

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Stubbert, Bryan D., Marks, Tobin J. (2007) Constrained Geometry Organoactinides as Versatile Catalysts for the Intramolecular Hydroamination/Cyclization of Primary and Secondary Amines Having Diverse Tethered C−C Unsaturation. Journal Of The American Chemical Society, 129 (14) 4253-4271 doi:10.1021/ja0665444
Seyam, Afif M., Stubbert, Bryan D., Jensen, Tryg R., O’Donnell, James J., Stern, Charlotte L., Marks, Tobin J. (2004) Organolanthanide constrained geometry complexes modified for catalysis: synthesis, structure, and aminoalkene hydroamination properties of a pyrrolidine-substituted constrained geometry organolutetium complex. Inorganica Chimica Acta, 357 (13). 4029-4035 doi:10.1016/j.ica.2004.08.018
Stubbert, Bryan D., Stern, Charlotte L., Marks, Tobin J. (2003) Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actinide-Mediated Intramolecular Hydroamination. Organometallics, 22. 4836-4838 doi:10.1021/om034093f
Hong, Sukwon, Marks, Tobin J. (2002) Highly Stereoselective Intramolecular Hydroamination/Cyclization of Conjugated Aminodienes Catalyzed by Organolanthanides. Journal Of The American Chemical Society, 124 (27) 7886-7887 doi:10.1021/ja020226x
Arredondo, Victor M., McDonald, Frank E., Marks, Tobin J. (1999) Intramolecular Hydroamination/Cyclization of Aminoallenes Catalyzed by Organolanthanide Complexes. Scope and Mechanistic Aspects. Organometallics, 18. 1949-1960 doi:10.1021/om981037j
Arredondo, Victor M., McDonald, Frank E., Marks, Tobin J. (1998) Organolanthanide-Catalyzed Intramolecular Hydroamination/Cyclization of Aminoallenes. Journal Of The American Chemical Society, 120 (19) 4871-4872 doi:10.1021/ja9743248
Tian, Shun, Arredondo, Victor M., Stern, Charlotte L., Marks, Tobin J. (1999) Constrained Geometry Organolanthanide Catalysts. Synthesis, Structural Characterization, and Enhanced Aminoalkene Hydroamination/Cyclization Activity. Organometallics, 18. 2568-2570 doi:10.1021/om990146a
Hong, Sukwon, Kawaoka, Amber M., Marks, Tobin J. (2003) Intramolecular Hydroamination/Cyclization of Conjugated Aminodienes Catalyzed by Organolanthanide Complexes. Scope, Diastereo- and Enantioselectivity, and Reaction Mechanism. Journal Of The American Chemical Society, 125 (51) 15878-15892 doi:10.1021/ja036266y
Li, Yanwu, Marks, Tobin J. (1996) Organolanthanide-Catalyzed Intramolecular Hydroamination/Cyclization of Aminoalkynes. Journal Of The American Chemical Society, 118 (39) 9295-9306 doi:10.1021/ja9612413
Tobisch, Sven (2012) Mechanistic elucidation of the yttrium(iii)-catalysed intramolecular aminoalkene hydroamination: DFT favours a stepwise σ-insertive mechanism. Dalton Transactions, 41 (30). 9182pp. doi:10.1039/c2dt30814b
Gagne, Michel R., Stern, Charlotte L., Marks, Tobin J. (1992) Organolanthanide-catalyzed hydroamination. A kinetic, mechanistic, and diastereoselectivity study of the cyclization of N-unprotected amino olefins. Journal Of The American Chemical Society, 114 (1) 275-294 doi:10.1021/ja00027a036
 
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