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Nesbitt, H. Wayne, Richet, Pascal, Henderson, Grant S., Bancroft, G. Michael (2025) Partial Molar Volumes in Highly Siliceous Melts and the Relationship to Liquid Immiscibility. American Journal of Science, 325. doi:10.2475/001c.129897

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Reference TypeJournal (article/letter/editorial)
TitlePartial Molar Volumes in Highly Siliceous Melts and the Relationship to Liquid Immiscibility
JournalAmerican Journal of Science
AuthorsNesbitt, H. WayneAuthor
Richet, PascalAuthor
Henderson, Grant S.Author
Bancroft, G. MichaelAuthor
Year2025 (April 4)Volume325
PublisherAmerican Journal of Science (AJS)
DOIdoi:10.2475/001c.129897Search in ResearchGate
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Mindat Ref. ID18248845Long-form Identifiermindat:1:5:18248845:4
GUID0
Full ReferenceNesbitt, H. Wayne, Richet, Pascal, Henderson, Grant S., Bancroft, G. Michael (2025) Partial Molar Volumes in Highly Siliceous Melts and the Relationship to Liquid Immiscibility. American Journal of Science, 325. doi:10.2475/001c.129897
Plain TextNesbitt, H. Wayne, Richet, Pascal, Henderson, Grant S., Bancroft, G. Michael (2025) Partial Molar Volumes in Highly Siliceous Melts and the Relationship to Liquid Immiscibility. American Journal of Science, 325. doi:10.2475/001c.129897

References Listed

These are the references the publisher has listed as being connected to the article. Please check the article itself for the full list of references which may differ. Not all references are currently linkable within the Digital Library.

Agee, Carl B (1998) Crystal-liquid density inversions in terrestrial and lunar magmas. Physics of the Earth and Planetary Interiors, 107 (1). 63-74 doi:10.1016/s0031-9201(97)00124-6
Birch, Francis (1947) Finite Elastic Strain of Cubic Crystals. Physical Review, 71 (11). 809-824 doi:10.1103/physrev.71.809
Bockris, J. O., Mellors, G. W. (1956) Electric Transport in Liquid Lead Silicates and Borates. The Journal of Physical Chemistry, 60 (9). 1321-1328 doi:10.1021/j150543a040
Not Yet Imported: - journal-article : 10.1039/tf9565200299

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Bottinga, Yan, Richet, Pascal, Weill, Daniel F. (1983) Calculation of the density and thermal expansion coefficient of silicate liquids. Bulletin de Minéralogie, 106 (1) 129-138 doi:10.3406/bulmi.1983.7675
Bottinga, Y., Weill, D. F. (1970) Densities of liquid silicate systems calculated from partial molar volumes of oxide components. American Journal of Science, 269 (2) 169-182 doi:10.2475/ajs.269.2.169
Bottinga, Y, Weill, D, Richet, P (1982) Density calculations for silicate liquids. I. Revised method for aluminosilicate compositions. Geochimica et Cosmochimica Acta, 46 (6) 909-919 doi:10.1016/0016-7037(82)90047-3
Bourova, Ekatarina, Richet, Pascal (1998) Quartz and Cristobalite: high-temperature cell parameters and volumes of fusion. Geophysical Research Letters, 25 (13) 2333-2336 doi:10.1029/98gl01581
Courtial, Philippe, Dingwell, Donald B. (1995) Nonlinear composition dependence of molar volume of melts in the CaOî—¸Al2O33î—¸SiO2 system. Geochimica et Cosmochimica Acta, 59 (18) 3685-3695 doi:10.1016/0016-7037(95)00272-2
Courtial, Philippe, Dingwell, Donald B. (1999) Densities of melts in the CaO-MgO-Al2O3-SiO2system. American Mineralogist, 84 (4) 465-476 doi:10.2138/am-1999-0401
Courtial, P. (2005) High-temperature density of lanthanide-bearing Na-silicate melts: Partial molar volumes for Ce2O3, Pr2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, Tb2O3, Dy2O3, Ho2O3, Er2O3, Tm2O3, and Yb2O3. American Mineralogist, 90 (10) 1597-1605 doi:10.2138/am.2005.1786
Courtial, Philippe, Dingwell, Donald B. (2006) A partial molar volume for La2O3 in silicate melts. Journal of Non-Crystalline Solids, 352 (4) 304-314 doi:10.1016/j.jnoncrysol.2005.12.002
Courtial, Philippe, Gottsmann, Joachim, Holzheid, Astrid, Dingwell, Donald B. (1999) Partial molar volumes of NiO and CoO liquids: implications for the pressure dependence of metal-silicate partitioning. Earth and Planetary Science Letters, 171 (1) 171-183 doi:10.1016/s0012-821x(99)00142-9
Demiralp, Ersan, Çağin, Tahir, Goddard, William A. (1999) Morse Stretch Potential Charge Equilibrium Force Field for Ceramics: Application to the Quartz-Stishovite Phase Transition and to Silica Glass. Physical Review Letters, 82 (8). 1708-1711 doi:10.1103/physrevlett.82.1708
Not Yet Imported: - journal-article : 10.1002/bbpc.19420480104

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Dingwell, Donald B., Brearley, Mark, Dickinson, James E. (1988) Melt densities in the Na2O-FeO-Fe2O3-SiO2 system and the partial molar volume of tetrahedrally-coordinated ferric iron in silicate melts. Geochimica et Cosmochimica Acta, 52 (10) 2467-2475 doi:10.1016/0016-7037(88)90305-5
Du, J., Cormack, A.N. (2004) The medium range structure of sodium silicate glasses: a molecular dynamics simulation. Journal of Non-Crystalline Solids, 349. 66-79 doi:10.1016/j.jnoncrysol.2004.08.264
Du, Jincheng, Corrales, L. René (2006) Compositional dependence of the first sharp diffraction peaks in alkali silicate glasses: A molecular dynamics study. Journal of Non-Crystalline Solids, 352 (30) 3255-3269 doi:10.1016/j.jnoncrysol.2006.05.025
George, Ann M., Richet, Pascal, Stebbins, Jonathan F. (1998) Cation dynamics and premelting in lithium metasilicate (Li2SiO3) and sodium metasilicate (Na2SiO3); a high-temperature NMR study. American Mineralogist, 83 (11) 1277-1284 doi:10.2138/am-1998-11-1216
Ghiorso, M. S. (2004) An equation of state for silicate melts. I. Formulation of a general model. American Journal of Science, 304 (8) 637-678 doi:10.2475/ajs.304.8-9.637
Ghiorso, M. S. (2004) An equation of state for silicate melts. II. Calibration of volumetric properties at 105 Pa. American Journal of Science, 304 (8) 679-751 doi:10.2475/ajs.304.8-9.679
Guillot, Bertrand, Sarda, Philippe (2006) The effect of compression on noble gas solubility in silicate melts and consequences for degassing at mid-ocean ridges. Geochimica et Cosmochimica Acta, 70 (5) 1215-1230 doi:10.1016/j.gca.2005.11.007
Guo, Xuan, Lange, Rebecca A., Ai, Yuhui (2013) The density and compressibility of CaO–FeO–SiO2 liquids at one bar: Evidence for four-coordinated Fe2+ in the CaFeO2 component. Geochimica et Cosmochimica Acta, 120. 206-219 doi:10.1016/j.gca.2013.06.007
HALLER, WOLFGANG, BLACKBURN, DOUGLAS H., SIMMONS, JOSEPH H. (1974) Miscibility Gaps in Alkali-Silicate Binaries-Data and Thermodynamic Interpretation. Journal of the American Ceramic Society, 57 (3). 120-126 doi:10.1111/j.1151-2916.1974.tb10832.x
Hess, Paul C. (1996) Upper and lower critical points: Thermodynamic constraints on the solution properties of silicate melts. Geochimica et Cosmochimica Acta, 60 (13) 2365-2377 doi:10.1016/0016-7037(96)00095-6
Hsieh, C.H., Jain, H., Miller, A.C., Kamitsos, E.I. (1994) X-ray photoelectron spectroscopy of Al- and B-substituted sodium trisilicate glasses. Journal of Non-Crystalline Solids, 168 (3) 247-257 doi:10.1016/0022-3093(94)90336-0
Hudon, Pierre, Baker, Don R. (2002) The nature of phase separation in binary oxide melts and glasses. I. Silicate systems. Journal of Non-Crystalline Solids, 303 (3) 299-345 doi:10.1016/s0022-3093(02)01043-8
J. E. Huheey (1993) Inorganic Chemistry: Principles of Structure and Reactivity
Jackson, W. E., de Leon, J. M., Brown, G. E., Waychunas, G. A., Conradson, S. D., Combes, J. -M. (1993) High-Temperature XAS Study of Fe2SiO4 Liquid: Reduced Coordination of Ferrous Iron. Science, 262 (5131). 229-233 doi:10.1126/science.262.5131.229
Jing, Zhicheng, Karato, Shun-ichiro (2011) A new approach to the equation of state of silicate melts: An application of the theory of hard sphere mixtures. Geochimica et Cosmochimica Acta, 75 (22) 6780-6802 doi:10.1016/j.gca.2011.09.004
Kim, Sung S., Sanders, Thomas H. (1999) Thermodynamic Modeling of the Miscibility Gaps and the Metastable Liquidi in the MgO-SiO2, CaO-SiO2, and SrO-SiO2Systems. Journal of the American Ceramic Society, 82 (7). 1901-1907 doi:10.1111/j.1151-2916.1999.tb02014.x
Knoche, R., Dingwell, D.B., Webb, S.L. (1995) Melt densities for leucogranites and granitic pegmatites: Partial molar volumes for SiO2, Al2O3, Na2O, K2O, Li2O, Rb2O, Cs2O, MgO, CaO, SrO, BaO, B2O3, P2O5, F2O−1, TiO2, Nb2O5, Ta2O5, and WO3. Geochimica et Cosmochimica Acta, 59 (22) 4645-4652 doi:10.1016/0016-7037(95)00328-2
Kracek, F. C. (1930) THE CRISTOBALITE LIQUIDUS IN THE ALKALI OXIDE-SILICA SYSTEMS AND THE HEAT OF FUSION OF CRISTOBALITE. Journal Of The American Chemical Society, 52 (4) 1436-1442 doi:10.1021/ja01367a021
Lange, Rebecca A. (1997) A revised model for the density and thermal expansivity of K 2 O-Na 2 O-CaO-MgO-Al 2 O 3 -SiO 2 liquids from 700 to 1900 K: extension to crustal magmatic temperatures. Contributions to Mineralogy and Petrology, 130 (1) 1-11 doi:10.1007/s004100050345
Lange, Rebecca A., Carmichael, Ian S.E. (1987) Densities of Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-TiO2-SiO2 liquids: New measurements and derived partial molar properties. Geochimica et Cosmochimica Acta, 51 (11) 2931-2946 doi:10.1016/0016-7037(87)90368-1
Not Yet Imported: - book-chapter : 10.1515/9781501508769-006

If you would like this item imported into the Digital Library, please contact us quoting Book ID 9781501508769
Lei, Xueling, Jee, Youngseok, Huang, Kevin (2015) Amorphous Na2Si2O5 as a fast Na+ conductor: an ab initio molecular dynamics simulation. Journal of Materials Chemistry A, 3. 19920-19927 doi:10.1039/c5ta04474j
Liu, Qiong, Lange, Rebecca A. (2001) The partial molar volume and thermal expansivity of TiO 2 in alkali silicate melts: Systematic variation with Ti coordination. Geochimica et Cosmochimica Acta, 65 (14) 2379-2393 doi:10.1016/s0016-7037(01)00565-8
Liu, Q. (2006) The partial molar volume of Fe2O3 in alkali silicate melts: Evidence for an average Fe3+ coordination number near five. American Mineralogist, 91 (2) 385-393 doi:10.2138/am.2006.1902
Marcus, Yizhak (2011) Electrostriction in Electrolyte Solutions. Chemical Reviews, 111 (4) 2761-2783 doi:10.1021/cr100130d
Micoulaut, M. (2008) Amorphous materials: Properties, structure, and durability: Constrained interactions, rigidity, adaptative networks, and their role for the description of silicates. American Mineralogist, 93 (11) 1732-1748 doi:10.2138/am.2008.2903
Not Yet Imported: - journal-article : 10.1590/s0103-97332007000300014

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Navrotsky, A., Geisinger, K. L., McMillan, P., Gibbs, G. V. (1985) The tetrahedral framework in glasses and melts ? inferences from molecular orbital calculations and implications for structure, thermodynamics, and physical properties. Physics and Chemistry of Minerals, 11 (6) 284-298 doi:10.1007/bf00307406
Nelson, S. A., Carmichael, I. S. E. (1979) Partial molar volumes of oxide components in silicate liquids. Contributions to Mineralogy and Petrology, 71 (2) 117-124 doi:10.1007/bf00375427
Nesbitt, H.Wayne, Fleet, Michael E (1981) An ion-association model for PbO-SiO2 melts: interpretation of thermochemical, conductivity, and density data. Geochimica et Cosmochimica Acta, 45 (2) 235-244 doi:10.1016/0016-7037(81)90168-x
Nesbitt, H.W., Henderson, G.S., Bancroft, G.M., O'Shaughnessy, C. (2017) Electron densities over Si and O atoms of tetrahedra and their impact on Raman stretching frequencies and Si-NBO force constants. Chemical Geology, 461. 65-74 doi:10.1016/j.chemgeo.2016.11.022
Nesbitt, H. Wayne, Richet, Pascal, Bancroft, G. Michael, Henderson, Grant S. (2022) Partial molar volumes of metal oxides in silicate melts: Effects of Coulombic interactions. American Journal of Science, 322 (5) 683-704 doi:10.2475/05.2022.02
K. S. Pitzer (1961) Thermodynamics
Rigden, Sally M., Ahrens, Thomas J., Stolper, E. M. (1989) High-pressure equation of state of molten anorthite and diopside. Journal of Geophysical Research, 94. 9508 doi:10.1029/jb094ib07p09508
J. S. Rowlinson (1969) Liquids and liquid mixtures
L. Sasek (1972) Sbornik Vysoke Skoly Chemlcko-Technologicke, Silikatu Structure and properties of silicate melts I L2, 165
L. Sasek (1972) Sbornik Vysoke Skoly Chemlcko-Technologicke, Silikatu Structure and properties of silicate melts II L2, 217
Shiraishi, Y., Ikeda, K., Tamura, A., Saitô, T. (1978) On the Viscosity and Density of the Molten FeO–SiO2 System. Transactions of the Japan Institute of Metals, 19. 264-274 doi:10.2320/matertrans1960.19.264
STEIN, DANIEL J., STEBBINS, JONATHAN F., CARMICHAEL, IAN S.E. (1986) Density of Molten Sodium Aluminosilicates. Journal of the American Ceramic Society, 69 (5). 396-399 doi:10.1111/j.1151-2916.1986.tb04767.x
Stixrude, L. (2005) Structure and Freezing of MgSiO3 Liquid in Earth's Lower Mantle. Science, 310 (5746). 297-299 doi:10.1126/science.1116952
Thompson, A. B., Aerts, M., Hack, A. C. (2007, July 1st) Liquid Immiscibility in Silicate Melts and Related Systems. Reviews in Mineralogy and Geochemistry Vol. 65. Mineralogical Society of America p.99-127. doi:10.2138/rmg.2007.65.4
J. B., Jr. Thompson (1967) Thermodynamic Properties of Simple Solutions 2, 340
Not Yet Imported: - journal-article : 10.1039/tf9585401822

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Toplis, Michael J. (2001) Quantitative links between microscopic properties and viscosity of liquids in the system SiO2–Na2O. Chemical Geology, 174 (1) 321-331 doi:10.1016/s0009-2541(00)00323-5
Veksler, Ilya V. (2004) Liquid immiscibility and its role at the magmatic–hydrothermal transition: a summary of experimental studies. Chemical Geology, 210 (1) 7-31 doi:10.1016/j.chemgeo.2004.06.002

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