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Gorskaya, M. G., Filatov, S. K., Rozhdestvenskaya, I. V., Vergasova, L. P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine, 56 (384) 411-416 doi:10.1180/minmag.1992.056.384.14

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Reference TypeJournal (article/letter/editorial)
TitleThe crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates
JournalMineralogical MagazineISSN0026-461X
AuthorsGorskaya, M. G.Author
Filatov, S. K.Author
Rozhdestvenskaya, I. V.Author
Vergasova, L. P.Author
Year1992 (September)Volume56
Issue384
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_56/56-384-411.pdf+
DOIdoi:10.1180/minmag.1992.056.384.14Search in ResearchGate
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Mindat Ref. ID1846Long-form Identifiermindat:1:5:1846:7
GUID0
Full ReferenceGorskaya, M. G., Filatov, S. K., Rozhdestvenskaya, I. V., Vergasova, L. P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine, 56 (384) 411-416 doi:10.1180/minmag.1992.056.384.14
Plain TextGorskaya, M. G., Filatov, S. K., Rozhdestvenskaya, I. V., Vergasova, L. P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine, 56 (384) 411-416 doi:10.1180/minmag.1992.056.384.14
In(1992, September) Mineralogical Magazine Vol. 56 (384) Mineralogical Society
Abstract/NotesAbstractThe crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, was determined in space group I2 using the total of 715 independent reflections up to R 0.12. Klyuchevskite is a structural analogue of piypite (caratiite) K4Cu4O2(SO4)4MeCl with the substitution K+ + Cu2+ → (Fe3+,Al) + MeCl. Compared to piypite, the ordering of Cu2+ and Fe3+ cations in the klyuchevskite structure results in the distortion of the unit cell and in lowering the symmetry of the chains to 1.This brings about a more compact packing of the chains. The chain-like arrangement of the structure determines physical properties of the mineral, its acicular habit, perfect cleavage, strong anisotropy of optical properties and orientation of optical indicatrix.


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