Gorskaya, M. G., Filatov, S. K., Rozhdestvenskaya, I. V., Vergasova, L. P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine, 56 (384) 411-416 doi:10.1180/minmag.1992.056.384.14

Reference Type | Journal (article/letter/editorial) | ||
---|---|---|---|
Title | The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates | ||
Journal | Mineralogical Magazine | ISSN | 0026-461X |
Authors | Gorskaya, M. G. | Author | |
Filatov, S. K. | Author | ||
Rozhdestvenskaya, I. V. | Author | ||
Vergasova, L. P. | Author | ||
Year | 1992 (September) | Volume | 56 |
Issue | 384 | ||
Publisher | Mineralogical Society | ||
Download URL | https://rruff.info/doclib/MinMag/Volume_56/56-384-411.pdf+ | ||
DOI | doi:10.1180/minmag.1992.056.384.14Search in ResearchGate | ||
Generate Citation Formats | |||
Mindat Ref. ID | 1846 | Long-form Identifier | mindat:1:5:1846:7 |
GUID | 0 | ||
Full Reference | Gorskaya, M. G., Filatov, S. K., Rozhdestvenskaya, I. V., Vergasova, L. P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine, 56 (384) 411-416 doi:10.1180/minmag.1992.056.384.14 | ||
Plain Text | Gorskaya, M. G., Filatov, S. K., Rozhdestvenskaya, I. V., Vergasova, L. P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine, 56 (384) 411-416 doi:10.1180/minmag.1992.056.384.14 | ||
In | (1992, September) Mineralogical Magazine Vol. 56 (384) Mineralogical Society | ||
Abstract/Notes | AbstractThe crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, was determined in space group I2 using the total of 715 independent reflections up to R 0.12. Klyuchevskite is a structural analogue of piypite (caratiite) K4Cu4O2(SO4)4MeCl with the substitution K+ + Cu2+ → (Fe3+,Al) + MeCl. Compared to piypite, the ordering of Cu2+ and Fe3+ cations in the klyuchevskite structure results in the distortion of the unit cell and in lowering the symmetry of the chains to 1.This brings about a more compact packing of the chains. The chain-like arrangement of the structure determines physical properties of the mineral, its acicular habit, perfect cleavage, strong anisotropy of optical properties and orientation of optical indicatrix. |
See Also
These are possibly similar items as determined by title/reference text matching only.