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Birch, W.D.; Clemens, J.D.; Mayne, M.J. (2025) Sekaninaite (Fe-dominant cordierite) from Devonian S-type rhyolites in Victoria, Australia. Mineralogical Magazine, Cambridge University Press. 1-45

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Reference TypeElectronic Article
TitleSekaninaite (Fe-dominant cordierite) from Devonian S-type rhyolites in Victoria, Australia
PublicationMineralogical Magazine
AuthorsBirch, W.D.Author
Clemens, J.D.Author
Mayne, M.J.Author
Year2025 (June)
Page(s)1-45
PublisherCambridge University Press
Original EntryBirch WD, Clemens JD, Mayne MJ. Sekaninaite (Fe-dominant cordierite) from Devonian S-type rhyolites in Victoria, Australia: genesis and comparisons with other occurrences in volcanic rocks. Mineralogical Magazine. Published online 2025:1-45. doi:10.1180/mgm.2025.10080
Classification
Not set
LoC
Not set
Mindat Ref. ID18572837Long-form Identifiermindat:1:5:18572837:3
GUID0
Full ReferenceBirch, W.D.; Clemens, J.D.; Mayne, M.J. (2025) Sekaninaite (Fe-dominant cordierite) from Devonian S-type rhyolites in Victoria, Australia. Mineralogical Magazine, Cambridge University Press. 1-45
Plain TextBirch, W.D.; Clemens, J.D.; Mayne, M.J. (2025) Sekaninaite (Fe-dominant cordierite) from Devonian S-type rhyolites in Victoria, Australia. Mineralogical Magazine, Cambridge University Press. 1-45
Abstract/NotesFe-dominant cordierite, the mineral sekaninaite, is relatively rare in calc-alkaline volcanic rocks, with only a handful of recorded localities. The compositionally zoned phenocrysts in the Late Devonian Rubicon Rhyolite in central Victoria, Australia are the most Fe-rich known, with core compositions having Mg# = 10 – 30. Similar cordierite-sekaninaite (Crd-Skn) phenocrysts occur in rhyolites and rhyodacites from San Vincenzo and Roccastrada in Tuscany and on Lipari Island in Italy, in the Nefza province in northern Tunisia, and in a
newly discovered Devonian rhyolite at Arthur’s Seat, Victoria. All show well-developed sector twinning in response to structural ordering during cooling. The Victorian sekaninaite crystals all show strong zonation from Fe-rich cores to rims richer in Mg, so-called reverse zoning. In contrast, the Italian and Tunisian examples have relatively weak normal zoning. In the Roccastrada and Lipari rocks, a second type of Crd-Skn occurs as turbid fragments and as groundmass crystals, with the latter showing reverse zoning. Reverse zoning in the Rubicon
and Arthurs Seat rhyolite phenocrysts and the Lipari groundmass crystals is attributed to the reheating of their host magmas due to interaction, such as mixing, with a higher-temperature magmas prior to eruption. The ranges of Crd-Skn compositions in all volcanic rocks bear no systematic relationship to the bulk compositions of their host rocks. Assuming that the whole rock compositions approximate the original magmatic liquids, and an initial H2O content of 5 wt% throughout, enabled a comparison to be made between the relative P-T conditions of
most occurrences, apart from Lipari. Results suggest that the Rubicon Rhyolite had the lowest P-T conditions with Roccastrada next, and San Vincenzo the highest. It appears that sekaninaite might be stable in silicic volcanic magmas over a wide range of melt compositions, pressures and temperatures but is favoured for low-Mg# bulk compositions at low P and low T.

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LocalityCitation Details
Arthurs Seat, Mornington Peninsula Shire, Victoria, Australia

Mineral Occurrences

LocalityMineral(s)
Arthurs Seat, Mornington Peninsula Shire, Victoria, Australia Almandine, Biotite, Feldspar Group, Garnet Group, Ignimbritic tuff, Microcline, Microcrystalline quartz, Orthoclase, Orthopyroxene Subgroup, Pinite, Plagioclase, Quartz, Rhyolite, Sekaninaite


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