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Tampier, Stefan, Burzlaff, Nicolai (2013) Heteroscorpionate complexes based on bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetate. Acta Crystallographica Section C Crystal Structure Communications, 69 (9) 981-985 doi:10.1107/s0108270113021148

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Reference TypeJournal (article/letter/editorial)
TitleHeteroscorpionate complexes based on bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetate
JournalActa Crystallographica Section C Crystal Structure Communications
AuthorsTampier, StefanAuthor
Burzlaff, NicolaiAuthor
Year2013 (September 15)Volume69
Issue9
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s0108270113021148Search in ResearchGate
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Mindat Ref. ID190996Long-form Identifiermindat:1:5:190996:2
GUID0
Full ReferenceTampier, Stefan, Burzlaff, Nicolai (2013) Heteroscorpionate complexes based on bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetate. Acta Crystallographica Section C Crystal Structure Communications, 69 (9) 981-985 doi:10.1107/s0108270113021148
Plain TextTampier, Stefan, Burzlaff, Nicolai (2013) Heteroscorpionate complexes based on bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetate. Acta Crystallographica Section C Crystal Structure Communications, 69 (9) 981-985 doi:10.1107/s0108270113021148
In(2013, September) Acta Crystallographica Section C Crystal Structure Communications Vol. 69 (9) International Union of Crystallography (IUCr)
Abstract/NotesThe heteroscorpionate ligand bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetate (bdtbpzdta) has been synthesized by reacting bis(3,5-di-tert-butylpyrazol-1-yl)methane withn-BuLi and CS2. The ligand was isolated as [bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetato](tetrahydrofuran)lithium(I) tetrahydrofuran monosolvate, [Li(C24H39N4S2)(C4H8O)]·C4H8O or [Li(bdtbpzdta)(THF)]·THF, in which the lithium cation is bound by the Îș3N,Nâ€Č,S-coordinated heteroscorpionate ligand. A similar coordination mode is observed for a zinc chloride complex bearing the bdtbpzdta ligand, namely [bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetato]chloridozinc(II), [Zn(C24H39N4S2)Cl] or [Zn(bdtbpzdta)Cl], which exhibits Îș3N,Nâ€Č,S-coordination and resembles the active site of zinc-containing peptide deformylases (PDFs).

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Fujisawa, Kiyoshi, Noguchi, Naoto, Noguchi, Yuki, Lehnert, Nicolai (2013) [Bis(3,5-diisopropylpyrazol-1-yl-ÎșN2)dihydroborato](triphenylphosphane-ÎșP)copper(I) Acta Crystallographica Section C Crystal Structure Communications, 69 (9) 943-946 doi:10.1107/s0108270113015965
Tampier, Stefan, Müller, Rainer, Thorn, Andrea, Hübner, Eike, Burzlaff, Nicolai (2008) Synthesis, Structure, and Reactivity of Ruthenium Carboxylato and 2-Oxocarboxylato Complexes Bearing the Bis(3,5-dimethylpyrazol-1-yl)acetato Ligand. Inorganic Chemistry, 47 (20) 9624-9641 doi:10.1021/ic8000224
Hiller, W., Rundel, W. (1993) Structure of 2,2-bis(3,5-di-tert-butylphenyl)propane-2',2''-dithiol. Acta Crystallographica Section C Crystal Structure Communications, 49 (6) 1127-1128 doi:10.1107/s0108270193001088
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Kopf, Henning, Pietraszuk, Cezary, HĂŒbner, Eike, Burzlaff, Nicolai (2006) Ruthenium Carbene, Vinylidene, and Allenylidene Complexes with a Bis(3,5-dimethylpyrazol-1-yl)acetato Heteroscorpionate Ligand. Organometallics, 25. 2533-2546 doi:10.1021/om060050y
Kozlevčar, Bojan, Jakomin, Klemen, Počkaj, Marta, Jagličić, Zvonko, Beyer, Andreas, Burzlaff, Nicolai, Kitanovski, Nives (2015) Dinuclear Nitrato Coordination Compounds with Bis(3,5-tert-butylpyrazol-1-yl)­acetate. European Journal of Inorganic Chemistry, 2015 (22) 3688-3693 doi:10.1002/ejic.201500368
Huuskonen, S.-P. J., Wilson, G. S., Anderson, H. L. (1998) 5,15-Bis(3,5-di-tert-butylphenyl)-10,20-bis(trimethylsilylethynyl)porphyrin. Acta Crystallographica Section C Crystal Structure Communications, 54 (5) 662-664 doi:10.1107/s0108270197017162
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Vachon, Jason, Schougaard, Steen Brian (2009) [Bis(3,5-dimethylpyrazol-1-yl-ÎșN2)hydro(pyrazol-1-yl-ÎșN2)borato][(3,5-dimethylpyrazol-1-yl-ÎșN2)dihydro(pyrazol-1-yl-ÎșN2)borato]nickel(II) Acta Crystallographica Section C Crystal Structure Communications, 65 (10) doi:10.1107/s0108270109030789
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Ng, Seik Weng (2013) A second monoclinic polymorph of 3,5-di-tert-butyl-2-hydroxybenzaldehyde. Acta Crystallographica Section E Structure Reports Online, 69 (9). doi:10.1107/s1600536813022010
 
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