Su, Bi-Yun, Wang, Jia-Xiang, Liu, Xiang, Li, Qian-Ding (2013) Isomeric 3- and 4-chloro-N-[1-(1H-pyrrol-2-yl)ethylidene]aniline. Acta Crystallographica Section C Crystal Structure Communications, 69 (5) 522-525 doi:10.1107/s0108270113007889
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Isomeric 3- and 4-chloro-N-[1-(1H-pyrrol-2-yl)ethylidene]aniline | ||
| Journal | Acta Crystallographica Section C Crystal Structure Communications | ||
| Authors | Su, Bi-Yun | Author | |
| Wang, Jia-Xiang | Author | ||
| Liu, Xiang | Author | ||
| Li, Qian-Ding | Author | ||
| Year | 2013 (May 15) | Volume | 69 |
| Issue | 5 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s0108270113007889Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 191102 | Long-form Identifier | mindat:1:5:191102:6 |
| GUID | 0 | ||
| Full Reference | Su, Bi-Yun, Wang, Jia-Xiang, Liu, Xiang, Li, Qian-Ding (2013) Isomeric 3- and 4-chloro-N-[1-(1H-pyrrol-2-yl)ethylidene]aniline. Acta Crystallographica Section C Crystal Structure Communications, 69 (5) 522-525 doi:10.1107/s0108270113007889 | ||
| Plain Text | Su, Bi-Yun, Wang, Jia-Xiang, Liu, Xiang, Li, Qian-Ding (2013) Isomeric 3- and 4-chloro-N-[1-(1H-pyrrol-2-yl)ethylidene]aniline. Acta Crystallographica Section C Crystal Structure Communications, 69 (5) 522-525 doi:10.1107/s0108270113007889 | ||
| In | (2013, May) Acta Crystallographica Section C Crystal Structure Communications Vol. 69 (5) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | The title isomers, namely 3-chloro-N-[1-(1H-pyrrol-2-yl)ethylidene]aniline, (I), and 4-chloro-N-[1-(1H-pyrrol-2-yl)ethylidene]aniline, (II), both C12H11ClN2, differ in the position of the chlorine substitution. Both compounds have the basic iminopyrrole structure, which shows a planar backbone with similar features. The dihedral angle formed by the planes of the pyrrole and benzene rings is 75.65 (7)° for (I) and 86.56 (8)° for (II). The H atom bound to the pyrrole N atom is positionally disordered and partial protonation occurs at the imino N atom in (I), while this phenomenon is absent from the structure of (II). Packing interactions for both compounds include intermolecular N—H...N hydrogen bonds and C—H...π interactions, forming centrosymmetric dimers for both (I) and (II). | ||
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