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Wang, Guan-Hua, Lei, Yong-Qian (2013) A fourfold interpenetrating diamondoid three-dimensional coordination polymer: poly[[[μ2-1,2-bis(pyridin-4-yl)ethene-κ2N:N′](μ2-5-hydroxyisophthalato-κ2O1:O3)zinc(II)] 1,2-bis(pyridin-4-yl)ethene hemisolvate]. Acta Crystallographica Section C Crystal Structure Communications, 69 (4) 360-362 doi:10.1107/s0108270113005143

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TitleA fourfold interpenetrating diamondoid three-dimensional coordination polymer: poly[[[μ2-1,2-bis(pyridin-4-yl)ethene-κ2N:N′](μ2-5-hydroxyisophthalato-κ2O1:O3)zinc(II)] 1,2-bis(pyridin-4-yl)ethene hemisolvate]
JournalActa Crystallographica Section C Crystal Structure Communications
AuthorsWang, Guan-HuaAuthor
Lei, Yong-QianAuthor
Year2013 (April 15)Volume69
Issue4
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s0108270113005143Search in ResearchGate
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Mindat Ref. ID191129Long-form Identifiermindat:1:5:191129:3
GUID0
Full ReferenceWang, Guan-Hua, Lei, Yong-Qian (2013) A fourfold interpenetrating diamondoid three-dimensional coordination polymer: poly[[[μ2-1,2-bis(pyridin-4-yl)ethene-κ2N:N′](μ2-5-hydroxyisophthalato-κ2O1:O3)zinc(II)] 1,2-bis(pyridin-4-yl)ethene hemisolvate]. Acta Crystallographica Section C Crystal Structure Communications, 69 (4) 360-362 doi:10.1107/s0108270113005143
Plain TextWang, Guan-Hua, Lei, Yong-Qian (2013) A fourfold interpenetrating diamondoid three-dimensional coordination polymer: poly[[[μ2-1,2-bis(pyridin-4-yl)ethene-κ2N:N′](μ2-5-hydroxyisophthalato-κ2O1:O3)zinc(II)] 1,2-bis(pyridin-4-yl)ethene hemisolvate]. Acta Crystallographica Section C Crystal Structure Communications, 69 (4) 360-362 doi:10.1107/s0108270113005143
In(2013, April) Acta Crystallographica Section C Crystal Structure Communications Vol. 69 (4) International Union of Crystallography (IUCr)
Abstract/NotesIn the title compound, {[Zn(C8H4O5)(C12H10N2)]·0.5C12H10N2}nor {[Zn(HO-BDC)(bpe)]·0.5bpe}n[HO-H2BDC is 5-hydroxyisophthalic acid and bpe is 1,2-bis(pyridin-4-yl)ethene], the asymmetric unit contains a ZnIIatom, one HO-BDC ligand, one coordinated bpe ligand and half a noncoordinating bpe molecule with crystallographic inversion symmetry. Each ZnIIcentre is four-coordinated by two O atoms from two distinct HO-BDC ligands and two N atoms from two different bpe ligands in a ZnO2N2coordination environment. The three-dimensional topology of the title compound corresponds to a fourfold interpenetrating diamondoid coordination polymer network, with the uncoordinated bpe ligands located in the cavities, hydrogen bonded to the main networkviathe hydroxy group of the HO-H2BDC ligand.


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