Motswainyana, William M., Onani, Martin O., Jacobs, Jeroen, Van Meervelt, Luc (2012) Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N′}palladium(II) acetonitrile monosolvate. Acta Crystallographica Section C Crystal Structure Communications, 68 (12) doi:10.1107/s0108270112045970
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N′}palladium(II) acetonitrile monosolvate | ||
| Journal | Acta Crystallographica Section C Crystal Structure Communications | ||
| Authors | Motswainyana, William M. | Author | |
| Onani, Martin O. | Author | ||
| Jacobs, Jeroen | Author | ||
| Van Meervelt, Luc | Author | ||
| Year | 2012 (December 1) | Volume | 68 |
| Issue | 12 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s0108270112045970Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 191506 | Long-form Identifier | mindat:1:5:191506:2 |
| GUID | 0 | ||
| Full Reference | Motswainyana, William M., Onani, Martin O., Jacobs, Jeroen, Van Meervelt, Luc (2012) Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N′}palladium(II) acetonitrile monosolvate. Acta Crystallographica Section C Crystal Structure Communications, 68 (12) doi:10.1107/s0108270112045970 | ||
| Plain Text | Motswainyana, William M., Onani, Martin O., Jacobs, Jeroen, Van Meervelt, Luc (2012) Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N′}palladium(II) acetonitrile monosolvate. Acta Crystallographica Section C Crystal Structure Communications, 68 (12) doi:10.1107/s0108270112045970 | ||
| In | (2012, December) Acta Crystallographica Section C Crystal Structure Communications Vol. 68 (12) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | The title complex, [PdCl2(C20H20N2)]·CH3CN, was synthesized by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline with dichlorido(cycloocta-1,5-diene)palladium(II) in dry CH2Cl2. The PdIIion is coordinated by two N atoms of the bidentate quinoline ligand and by two chloride anions, generating a distorted square-planar coordination geometry around the metal centre. There is a detectabletransinfluence for the chloride ligands. The crystal packing is characterized by π–π stacking between the quinoline rings. The use of acetonitrile as the crystallization solvent was essential for obtaining good-quality crystals. | ||
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