Piryazev, Dmitry A., Ogienko, Mikhail A., Virovets, Alexander V., Pushkarevsky, Nikolay A., Konchenko, Sergey N. (2012) [N,N′-Bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine-1κ2N,N′]heptacarbonyl-1κC,2κ3C,3κ3C-di-μ3-tellurido-triiiron(II)(2Fe—Fe) Acta Crystallographica Section C Crystal Structure Communications, 68 (11) doi:10.1107/s0108270112040012
Reference Type | Journal (article/letter/editorial) | ||
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Title | [N,N′-Bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine-1κ2N,N′]heptacarbonyl-1κC,2κ3C,3κ3C-di-μ3-tellurido-triiiron(II)(2Fe—Fe) | ||
Journal | Acta Crystallographica Section C Crystal Structure Communications | ||
Authors | Piryazev, Dmitry A. | Author | |
Ogienko, Mikhail A. | Author | ||
Virovets, Alexander V. | Author | ||
Pushkarevsky, Nikolay A. | Author | ||
Konchenko, Sergey N. | Author | ||
Year | 2012 (November 15) | Volume | 68 |
Issue | 11 | ||
Publisher | International Union of Crystallography (IUCr) | ||
DOI | doi:10.1107/s0108270112040012Search in ResearchGate | ||
Generate Citation Formats | |||
Mindat Ref. ID | 191519 | Long-form Identifier | mindat:1:5:191519:2 |
GUID | 0 | ||
Full Reference | Piryazev, Dmitry A., Ogienko, Mikhail A., Virovets, Alexander V., Pushkarevsky, Nikolay A., Konchenko, Sergey N. (2012) [N,N′-Bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine-1κ2N,N′]heptacarbonyl-1κC,2κ3C,3κ3C-di-μ3-tellurido-triiiron(II)(2Fe—Fe) Acta Crystallographica Section C Crystal Structure Communications, 68 (11) doi:10.1107/s0108270112040012 | ||
Plain Text | Piryazev, Dmitry A., Ogienko, Mikhail A., Virovets, Alexander V., Pushkarevsky, Nikolay A., Konchenko, Sergey N. (2012) [N,N′-Bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine-1κ2N,N′]heptacarbonyl-1κC,2κ3C,3κ3C-di-μ3-tellurido-triiiron(II)(2Fe—Fe) Acta Crystallographica Section C Crystal Structure Communications, 68 (11) doi:10.1107/s0108270112040012 | ||
In | (2012, November) Acta Crystallographica Section C Crystal Structure Communications Vol. 68 (11) International Union of Crystallography (IUCr) | ||
Abstract/Notes | The sterically hindered title complex, [Fe3Te2(C36H40N2)(CO)7], was obtained by substitution of two carbonyl groups in the [Fe3(μ3-Te)2(CO)9] cluster by the bulky redox-activeN,N′-bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine (dpp-BIAN) ligand. The asymmetric unit contains two molecules of the same geometry. The C=N bond lengths in dpp-BIAN indicate a rather low level of electron transfer from the cluster core to the dpp-BIAN ligand. |
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