Granifo, Juan, Gaviño, Rubén, Freire, Eleonora, Baggio, Ricardo (2012) Monodentate and bridging behaviour of the sulfur-containing ligand 4′-[4-(methylsulfanyl)phenyl]-4,2′:6′,4′′-terpyridine in two discrete zinc(II) complexes with acetylacetonate. Acta Crystallographica Section C Crystal Structure Communications, 68 (10) doi:10.1107/s010827011203483x
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Monodentate and bridging behaviour of the sulfur-containing ligand 4′-[4-(methylsulfanyl)phenyl]-4,2′:6′,4′′-terpyridine in two discrete zinc(II) complexes with acetylacetonate | ||
| Journal | Acta Crystallographica Section C Crystal Structure Communications | ||
| Authors | Granifo, Juan | Author | |
| Gaviño, Rubén | Author | ||
| Freire, Eleonora | Author | ||
| Baggio, Ricardo | Author | ||
| Year | 2012 (October 15) | Volume | 68 |
| Issue | 10 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s010827011203483xSearch in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 191540 | Long-form Identifier | mindat:1:5:191540:6 |
| GUID | 0 | ||
| Full Reference | Granifo, Juan, Gaviño, Rubén, Freire, Eleonora, Baggio, Ricardo (2012) Monodentate and bridging behaviour of the sulfur-containing ligand 4′-[4-(methylsulfanyl)phenyl]-4,2′:6′,4′′-terpyridine in two discrete zinc(II) complexes with acetylacetonate. Acta Crystallographica Section C Crystal Structure Communications, 68 (10) doi:10.1107/s010827011203483x | ||
| Plain Text | Granifo, Juan, Gaviño, Rubén, Freire, Eleonora, Baggio, Ricardo (2012) Monodentate and bridging behaviour of the sulfur-containing ligand 4′-[4-(methylsulfanyl)phenyl]-4,2′:6′,4′′-terpyridine in two discrete zinc(II) complexes with acetylacetonate. Acta Crystallographica Section C Crystal Structure Communications, 68 (10) doi:10.1107/s010827011203483x | ||
| In | (2012, October) Acta Crystallographica Section C Crystal Structure Communications Vol. 68 (10) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | The Zn complexes bis(acetylacetonato-κ2O,O′)bis{4′-[4-(methylsulfanyl)phenyl]-4,2′:6′,4′′-terpyridine-κN1}zinc(II), [Zn(C5H7O2)2(C22H17N3S)2], (I), and {μ-4′-[4-(methylsulfanyl)phenyl]-4,2′:6′,4′′-terpyridine-κ2N1:N1′′}bis[bis(acetylacetonato-κ2O,O′)zinc(II)], [Zn2(C5H7O2)4(C22H17N3S)], (II), are discrete entities with different nuclearities. Compound (I) consists of two centrosymmetrically related monodentate 4′-[4-(methylsulfanyl)phenyl]-4,2′:6′,4′′-terpyridine (L1) ligands binding to one ZnIIatom sitting on an inversion centre and two centrosymmetrically related chelating acetylacetonate (acac) groups which bindviacarbonyl O-atom donors, giving an N2O4octahedral environment for ZnII. Compound (II), however, consists of a bis-monodentateL1 ligand bridging two ZnIIatoms from two different Zn(acac)2fragments. Intra- and intermolecular interactions are weak, mainly of the C—H...π and π–π types, mediating similar layered structures. In contrast to related structures in the literature, sulfur-mediated nonbonding interactions in (II) do not seem to have any significant influence on the supramolecular structure. | ||
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