Reference Type | Journal (article/letter/editorial) |
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Title | Iowaite, a re-investigation |
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Journal | Mineralogical Magazine | ISSN | 0026-461X |
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Authors | Braithwaite, R. S. W. | Author |
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Dunn, P. J. | Author |
Pritchard, R. G. | Author |
Paar, W. H. | Author |
Year | 1994 (March) | Volume | 58 |
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Issue | 390 |
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Publisher | Mineralogical Society |
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Download URL | https://rruff.info/doclib/MinMag/Volume_58/58-390-79.pdf+ |
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DOI | doi:10.1180/minmag.1994.058.390.08Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 2005 | Long-form Identifier | mindat:1:5:2005:7 |
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GUID | 0 |
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Full Reference | Braithwaite, R. S. W., Dunn, P. J., Pritchard, R. G., Paar, W. H. (1994) Iowaite, a re-investigation. Mineralogical Magazine, 58 (390) 79-85 doi:10.1180/minmag.1994.058.390.08 |
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Plain Text | Braithwaite, R. S. W., Dunn, P. J., Pritchard, R. G., Paar, W. H. (1994) Iowaite, a re-investigation. Mineralogical Magazine, 58 (390) 79-85 doi:10.1180/minmag.1994.058.390.08 |
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In | (1994, March) Mineralogical Magazine Vol. 58 (390) Mineralogical Society |
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Abstract/Notes | AbstractIowaite has been re-examined using new, well crystallized material from the Palabora open pit mine, Transvaal. Microprobe, carbon analyser and thermal analyses, powder and single-crystal X-ray diffraction, infrared, UV-visible and mass spectroscopic and optical studies were made. The ideal formula is (OH)16Cl2·4H2O. It is trigonal, R3̄m, a = 3.1183(9), c = 24.113(8) Å, V = 203.1(2) Å3, Z = 3/8; Dobs 2.09 g/cm3.; Dcalc 2.04 g/cm3; hardness (Mohs)=2 1/2. The interlayer Cl− ions are displaced from the threefold axis. It is uniaxial negative, with ω = 1.561 ± 0.002, ε = 1.543 ± 0.002; coloured crystals are intensely pleochroic, due to intervalence charge transfer between the Fe3+ and Fe2+ substituting for Mg2+, with O pale yellow, E deep blue-green. |
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