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Della Ventura, G., Ventruti, G., Bellatreccia, F., Scordari, F., Cestelli Guidi, M. (2013) FTIR transmission spectroscopy of sideronatrite, a sodium-iron hydrous sulfate. Mineralogical Magazine, 77 (4) 499-507 doi:10.1180/minmag.2013.077.4.09

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Reference TypeJournal (article/letter/editorial)
TitleFTIR transmission spectroscopy of sideronatrite, a sodium-iron hydrous sulfate
JournalMineralogical Magazine
AuthorsDella Ventura, G.Author
Ventruti, G.Author
Bellatreccia, F.Author
Scordari, F.Author
Cestelli Guidi, M.Author
Year2013 (June)Volume77
Issue4
PublisherMineralogical Society
DOIdoi:10.1180/minmag.2013.077.4.09Search in ResearchGate
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Mindat Ref. ID244403Long-form Identifiermindat:1:5:244403:5
GUID0
Full ReferenceDella Ventura, G., Ventruti, G., Bellatreccia, F., Scordari, F., Cestelli Guidi, M. (2013) FTIR transmission spectroscopy of sideronatrite, a sodium-iron hydrous sulfate. Mineralogical Magazine, 77 (4) 499-507 doi:10.1180/minmag.2013.077.4.09
Plain TextDella Ventura, G., Ventruti, G., Bellatreccia, F., Scordari, F., Cestelli Guidi, M. (2013) FTIR transmission spectroscopy of sideronatrite, a sodium-iron hydrous sulfate. Mineralogical Magazine, 77 (4) 499-507 doi:10.1180/minmag.2013.077.4.09
Abstract/NotesAbstractThis paper relates an infrared (IR) (6000–2500; 1400–400 cm–1) spectroscopic study of sideronatrite, Na2Fe3+(SO4)2(OH)·3H2O. Spectra in the 600–1250 cm–1range are dominated by fundamental S–O absorption bands. Factor-group analysis based on the space group P212121(D42) is in accordance with the observed band multiplicity. A broad and convolute absorption centred around 3400 cm–1and a sharp band at 3605 cm–1are observed in the 2900–3900 cm–1frequency region. The resolution of the broad band is significantly improved at liquid nitrogen temperature; seven components can be fitted to the pattern and these can be assigned to H2O/OH molecules in the structure. All components in the broad band and the sharp absorption at 3605 cm–1are strongly polarized forE//a, in accordance with the structure analysis results. Infrared transmission spectroscopy is a useful tool to identify these sulfate minerals occurring in specific geological environments.


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