Reference Type | Journal (article/letter/editorial) |
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Title | FTIR transmission spectroscopy of sideronatrite, a sodium-iron hydrous sulfate |
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Journal | Mineralogical Magazine |
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Authors | Della Ventura, G. | Author |
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Ventruti, G. | Author |
Bellatreccia, F. | Author |
Scordari, F. | Author |
Cestelli Guidi, M. | Author |
Year | 2013 (June) | Volume | 77 |
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Issue | 4 |
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Publisher | Mineralogical Society |
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DOI | doi:10.1180/minmag.2013.077.4.09Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 244403 | Long-form Identifier | mindat:1:5:244403:5 |
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GUID | 0 |
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Full Reference | Della Ventura, G., Ventruti, G., Bellatreccia, F., Scordari, F., Cestelli Guidi, M. (2013) FTIR transmission spectroscopy of sideronatrite, a sodium-iron hydrous sulfate. Mineralogical Magazine, 77 (4) 499-507 doi:10.1180/minmag.2013.077.4.09 |
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Plain Text | Della Ventura, G., Ventruti, G., Bellatreccia, F., Scordari, F., Cestelli Guidi, M. (2013) FTIR transmission spectroscopy of sideronatrite, a sodium-iron hydrous sulfate. Mineralogical Magazine, 77 (4) 499-507 doi:10.1180/minmag.2013.077.4.09 |
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Abstract/Notes | AbstractThis paper relates an infrared (IR) (6000–2500; 1400–400 cm–1) spectroscopic study of sideronatrite, Na2Fe3+(SO4)2(OH)·3H2O. Spectra in the 600–1250 cm–1range are dominated by fundamental S–O absorption bands. Factor-group analysis based on the space group P212121(D42) is in accordance with the observed band multiplicity. A broad and convolute absorption centred around 3400 cm–1and a sharp band at 3605 cm–1are observed in the 2900–3900 cm–1frequency region. The resolution of the broad band is significantly improved at liquid nitrogen temperature; seven components can be fitted to the pattern and these can be assigned to H2O/OH molecules in the structure. All components in the broad band and the sharp absorption at 3605 cm–1are strongly polarized forE//a, in accordance with the structure analysis results. Infrared transmission spectroscopy is a useful tool to identify these sulfate minerals occurring in specific geological environments. |
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