Reference Type | Journal (article/letter/editorial) |
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Title | The crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, from Cap Garonne, France |
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Journal | Mineralogical Magazine |
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Authors | Mills, Stuart J. | Author |
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Christy, Andrew G. | Author |
Favreau, Georges | Author |
Year | 2018 (February) | Volume | 82 |
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Issue | 1 |
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Publisher | Mineralogical Society |
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DOI | doi:10.1180/minmag.2017.081.033Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 245004 | Long-form Identifier | mindat:1:5:245004:3 |
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GUID | 0 |
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Full Reference | Mills, Stuart J., Christy, Andrew G., Favreau, Georges (2018) The crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, from Cap Garonne, France. Mineralogical Magazine, 82 (1) 181-187 doi:10.1180/minmag.2017.081.033 |
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Plain Text | Mills, Stuart J., Christy, Andrew G., Favreau, Georges (2018) The crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, from Cap Garonne, France. Mineralogical Magazine, 82 (1) 181-187 doi:10.1180/minmag.2017.081.033 |
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Abstract/Notes | ABSTRACTThe crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, has been solved to an R1 of 0.0307, using the world's largest crystals from the Cap Garonne mine, France. Ceruleite crystallizes in space group P21/n, with the unit cell a = 7.2000(14), b = 11.345(2), c = 9.856(2) Å, β = 105.57(3)°, V = 775.6(3) Å3 and Z = 1. Ceruleite has a unique structure that consists of Al(O,OH)6 octahedra that are sharing edges to form rhombus-shaped tetramers. AsO4 tetrahedra share two corners with one such rhombus and the other two corners with each of two other rhombi, linking them into a very open mesoporous framework. Cu(OH)2(H2O)2 squares lie in the channels and link Al4 rhombi along || b. H2O molecules are also located in the channels. |
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