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Mills, Stuart J., Christy, Andrew G., Favreau, Georges (2018) The crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, from Cap Garonne, France. Mineralogical Magazine, 82 (1) 181-187 doi:10.1180/minmag.2017.081.033

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Reference TypeJournal (article/letter/editorial)
TitleThe crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, from Cap Garonne, France
JournalMineralogical Magazine
AuthorsMills, Stuart J.Author
Christy, Andrew G.Author
Favreau, GeorgesAuthor
Year2018 (February)Volume82
Issue1
PublisherMineralogical Society
DOIdoi:10.1180/minmag.2017.081.033Search in ResearchGate
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Mindat Ref. ID245004Long-form Identifiermindat:1:5:245004:3
GUID0
Full ReferenceMills, Stuart J., Christy, Andrew G., Favreau, Georges (2018) The crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, from Cap Garonne, France. Mineralogical Magazine, 82 (1) 181-187 doi:10.1180/minmag.2017.081.033
Plain TextMills, Stuart J., Christy, Andrew G., Favreau, Georges (2018) The crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, from Cap Garonne, France. Mineralogical Magazine, 82 (1) 181-187 doi:10.1180/minmag.2017.081.033
Abstract/NotesABSTRACTThe crystal structure of ceruleite, CuAl4[AsO4]2(OH)8(H2O)4, has been solved to an R1 of 0.0307, using the world's largest crystals from the Cap Garonne mine, France. Ceruleite crystallizes in space group P21/n, with the unit cell a = 7.2000(14), b = 11.345(2), c = 9.856(2) Å, β = 105.57(3)°, V = 775.6(3) Å3 and Z = 1. Ceruleite has a unique structure that consists of Al(O,OH)6 octahedra that are sharing edges to form rhombus-shaped tetramers. AsO4 tetrahedra share two corners with one such rhombus and the other two corners with each of two other rhombi, linking them into a very open mesoporous framework. Cu(OH)2(H2O)2 squares lie in the channels and link Al4 rhombi along || b. H2O molecules are also located in the channels.

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Ceruleite

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LocalityMineral(s)
Cap Garonne Mine, Le Pradet, Toulon, Var, Provence-Alpes-Côte d'Azur, France Ceruleite


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