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Okamoto, Kunio, Matsui, Yoshihisa, Shingu, Haruo (1965) Kinetic Studies of Solvolysis. X. Transition from a van’t Hoff to an Arrhenius Intermediate Caused by Steric Hindrance at the Product-Formation Step of SN1 Reactions. Bulletin of the Chemical Society of Japan, 38 (11). 1844-1852 doi:10.1246/bcsj.38.1844

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Reference TypeJournal (article/letter/editorial)
TitleKinetic Studies of Solvolysis. X. Transition from a van’t Hoff to an Arrhenius Intermediate Caused by Steric Hindrance at the Product-Formation Step of SN1 Reactions
JournalBulletin of the Chemical Society of Japan
AuthorsOkamoto, KunioAuthor
Matsui, YoshihisaAuthor
Shingu, HaruoAuthor
Year1965 (November)Volume38
Issue11
PublisherThe Chemical Society of Japan
DOIdoi:10.1246/bcsj.38.1844Search in ResearchGate
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Mindat Ref. ID4474767Long-form Identifiermindat:1:5:4474767:7
GUID0
Full ReferenceOkamoto, Kunio, Matsui, Yoshihisa, Shingu, Haruo (1965) Kinetic Studies of Solvolysis. X. Transition from a van’t Hoff to an Arrhenius Intermediate Caused by Steric Hindrance at the Product-Formation Step of SN1 Reactions. Bulletin of the Chemical Society of Japan, 38 (11). 1844-1852 doi:10.1246/bcsj.38.1844
Plain TextOkamoto, Kunio, Matsui, Yoshihisa, Shingu, Haruo (1965) Kinetic Studies of Solvolysis. X. Transition from a van’t Hoff to an Arrhenius Intermediate Caused by Steric Hindrance at the Product-Formation Step of SN1 Reactions. Bulletin of the Chemical Society of Japan, 38 (11). 1844-1852 doi:10.1246/bcsj.38.1844
In(1965, November) Bulletin of the Chemical Society of Japan Vol. 38 (11) The Chemical Society of Japan

See Also

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Okamoto, Kunio, Matsui, Yoshihisa, Shingu, Haruo (1965) Radical Formation from the Intermediates of Sn1 Reacions. A One-Electron Transfer Reaction between a Carbonium-ion Type Intermediate and Nucleophiles. Bulletin of the Chemical Society of Japan, 38 (1). 153-154 doi:10.1246/bcsj.38.153
Okamoto, Kunio, Saitô, Seiki, Shingu, Haruo (1969) Kinetic Studies of Solvolysis. XVI. Phenolysis ofcis- andtrans-4-t-Butylcyclohexyp-Toluenesulfonates. Rates and Product Distribution. Bulletin of the Chemical Society of Japan, 42 (11). 3288-3297 doi:10.1246/bcsj.42.3288
Okamoto, Kunio, Nitta, Issei, Shingu, Haruo (1968) Kinetic Studies of Solvolysis. XV. Racemization Caused by the Molecular-Complex Formation in the Acetolysis of Optically Active 2,4,7-Trinitro-9-fluorenyl (+)-Camphor-10-sulfonate. Bulletin of the Chemical Society of Japan, 41 (6). 1433-1440 doi:10.1246/bcsj.41.1433
Okamoto, Kunio, Takeuchi, Ken-ichi, Shingu, Haruo (1962) Kinetic Studies on Solvolysis. VIII. Phenolysis of Optically Active α-Phenethyl Chloride in Phenol-Benzene Solven—Three-stage Mechanism in the SN1-Type Solvolysis. Bulletin of the Chemical Society of Japan, 35 (4). 525-531 doi:10.1246/bcsj.35.525
Okamoto, Kunio, Komatsu, Kôichi, Shingu, Haruo (1966) A Retentive SN1 Hydrolysis in Aqueous Acrylonitrile and the Polymerization of Acrylonitrile Initiated by the SN1 Hydrolysis Intermediate. Bulletin of the Chemical Society of Japan, 39 (12). 2785 doi:10.1246/bcsj.39.2785
Okamoto, Kunio, Kinoshita, Tomomi, Shingu, Haruo (1970) The Retentive Solvolysis. VII. Structural Effect of the Leaving Group on the Steric Course of the SN1 Phenolysis of 1-Phenylethyl Systems. Bulletin of the Chemical Society of Japan, 43 (5). 1545-1553 doi:10.1246/bcsj.43.1545
Okamoto, Kunio, Komatsu, K\={o}ichi, Shingu, Haruo (1967) Kinetic Studies of Solvolysis. XIV. The Solvolysis of Optically Active α-Phenylethyl Chloride in Binary Mixtures of Methanol and Phenol —The SN1 Methanolysis with the Retention of the Configuration—. Bulletin of the Chemical Society of Japan, 40 (7). 1677-1680 doi:10.1246/bcsj.40.1677
Okamoto, Kunio, Shingu, Haruo (1961) Kinetic Studies on Solvolysis. VI. Kinetic Evidence of the Distinct Rôle of the Hydrogen Atom of Hydroxylic Solvent Molecules as an Attacking Center at the First Ionization Stage. Bulletin of the Chemical Society of Japan, 34 (8). 1131-1136 doi:10.1246/bcsj.34.1131
Okamoto, Kunio, Yamada, Hiroto, Nitta, Issei, Shingu, Haruo (1966) Kinetic Studies of Solvolysis. XI. The Steric Course of the Phenolyses of Optically Active α-Phenylethyl Chloride in Mixtures of Various Phenols and Organic Solvents—A Mechanism for the SN1 Reaction with a Net Retention of Configuration. Bulletin of the Chemical Society of Japan, 39 (2). 299-306 doi:10.1246/bcsj.39.299
Okamoto, Kunio, Takeuchi, Ken-ichi, Shingu, Haruo (1961) Kinetic Studies on Solvolysis. VII. On the Kinetic Resolution at the First Stage of the SNl-type Solvolysis of α-Phenethyl Chloride in Optically Active Carboxylic Acid Solvents. Bulletin of the Chemical Society of Japan, 34 (8). 1137-1143 doi:10.1246/bcsj.34.1137
Okamoto, Kunio, Hayashi, Masayuki, Komatsu, Koichi, Shingu, Haruo (1967) Kinetic Studies of Solvolysis. XIII. The Solvolyses of Optically-active α-Phenylethyl Chloride in Binary Mixtures of Phenol and Water—The SN1 Hydrolysis with the Retention of the Configuration. Bulletin of the Chemical Society of Japan, 40 (3). 624-628 doi:10.1246/bcsj.40.624
 
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