| Reference Type | Journal (article/letter/editorial) |
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| Title | High-temperature study of basic ferric sulfate, FeOHSO4 |
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| Journal | Physics and Chemistry of Minerals |
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| Authors | Ventruti, Gennaro | Author |
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| Della Ventura, Giancarlo | Author |
| Gomez, Mario Alberto | Author |
| Capitani, Giancarlo | Author |
| Sbroscia, Marco | Author |
| Sodo, Armida | Author |
| Year | 2020 (October) | Volume | 47 |
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| Page(s) | 43 | Issue | 10 |
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| Publisher | Springer Science and Business Media LLC |
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| URL | |
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| DOI | doi:10.1007/s00269-020-01113-7Search in ResearchGate |
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| Generate Citation Formats |
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| Classification | Not set | LoC | Not set |
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| Mindat Ref. ID | 4570422 | Long-form Identifier | mindat:1:5:4570422:6 |
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| GUID | 0 |
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| Full Reference | Ventruti, Gennaro; Della Ventura, Giancarlo; Gomez, Mario Alberto; Capitani, Giancarlo; Sbroscia, Marco; Sodo, Armida (2020) High-temperature study of basic ferric sulfate, FeOHSO4. Physics and Chemistry of Minerals, 47 (10). 43 doi:10.1007/s00269-020-01113-7 |
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| Plain Text | Ventruti, Gennaro; Della Ventura, Giancarlo; Gomez, Mario Alberto; Capitani, Giancarlo; Sbroscia, Marco; Sodo, Armida (2020) High-temperature study of basic ferric sulfate, FeOHSO4. Physics and Chemistry of Minerals, 47 (10). 43 doi:10.1007/s00269-020-01113-7 |
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| In | (2020, October) Physics and Chemistry of Minerals Vol. 47 (10) Springer Science and Business Media LLC |
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| Abstract/Notes | AbstractWe report in this paper a new crystal-chemical study of synthetic basic ferric sulfate FeOHSO4. The structure solution performed by the Endeavour program, from new X-ray powder diffraction (XRPD) data, indicated that the correct space group of the monoclinic polytype of FeOHSO4 is C2/c. Selected Area Electron Diffraction (SAED) patterns are also consistent with this structure solution. The arrangement of Fe and S atoms, based on linear chains of Fe3+ octahedra cross-linked by SO4 tetrahedra, corresponds to that of the order/disorder (OD) family. The positions of the hydrogen atoms were located based on DFT calculations. IR and Raman spectra are presented and discussed according to this new structure model. The decomposition of FeOHSO4 during heating was further investigated by means of variable temperature XRPD, thermogravimetry, and differential thermal analysis as well as IR and Raman spectroscopies. |
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