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Edwards, R., Gillard, R. D., Williams, P. A. (1996) The stabilities of secondary tin minerals. Part 2: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4. Mineralogical Magazine, 60 (400) 427-432 doi:10.1180/minmag.1996.060.400.04

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Reference TypeJournal (article/letter/editorial)
TitleThe stabilities of secondary tin minerals. Part 2: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4
JournalMineralogical MagazineISSN0026-461X
AuthorsEdwards, R.Author
Gillard, R. D.Author
Williams, P. A.Author
Year1996 (June)Volume60
Issue400
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_60/60-400-427.pdf+
DOIdoi:10.1180/minmag.1996.060.400.04Search in ResearchGate
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Mindat Ref. ID46Long-form Identifiermindat:1:5:46:2
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Full ReferenceEdwards, R., Gillard, R. D., Williams, P. A. (1996) The stabilities of secondary tin minerals. Part 2: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4. Mineralogical Magazine, 60 (400) 427-432 doi:10.1180/minmag.1996.060.400.04
Plain TextEdwards, R., Gillard, R. D., Williams, P. A. (1996) The stabilities of secondary tin minerals. Part 2: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4. Mineralogical Magazine, 60 (400) 427-432 doi:10.1180/minmag.1996.060.400.04
In(1996, June) Mineralogical Magazine Vol. 60 (400) Mineralogical Society
Abstract/NotesAbstractTritin(II)dihydroxyoxosulphate, Sn3O(OH)2SO4, is a rare corrosion product found on the surfaces of certain tin alloys. A new synthesis based on the hydrolysis of SnSO4 is described. The stability constant determination of Sn3O(OH)2SO4,s, at 298.2K and 105Pa is determined using direct measurements via electrodes, of the activities of tin(II) and sulphate ions. ΔfG0(298.2K) is equal to −1563.1 ± 0.9 KJ mol−1.

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Edwards, R., Gillard, R. D., Williams, P. A. (1992) The stabilities of secondary tin minerals: abhurite and its relationships to Sn(II) and Sn(IV) oxides and oxyhydroxides. Mineralogical Magazine, 56 (383) 221-226 doi:10.1180/minmag.1992.056.383.08
Edwards, R., Gillard, R. D., Williams, P. A., Pollard, A. M. (1992) Studies of secondary mineral formation in the PbO-H2O-HCl system. Mineralogical Magazine, 56 (382). 53-65 doi:10.1180/minmag.1992.056.382.07
Pollard, A. M., Thomas, R. G., Williams, P. A. (1992) The stabilities of antlerite and Cu3SO4(OH)4.2H2O: their formation and relationships to other copper(II) sulfate minerals. Mineralogical Magazine, 56 (384) 359-365 doi:10.1180/minmag.1992.056.384.08
Pollard, A. M., Thomas, R. G., Williams, P. A. (1990) Connellite: stability relationships with other secondary copper minerals. Mineralogical Magazine, 54 (376) 425-430 doi:10.1180/minmag.1990.054.376.08
Gillard, R. D. (1985) The determination of ferrous and ferric iron in rocks and minerals–a comment. Mineralogical Magazine, 49 (350) 101-102 doi:10.1180/minmag.1985.049.350.15
Pollard, A. M., Thomas, R. G., Williams, P. A. (1989) Synthesis and stabilities of the basic copper(II) chlorides atacamite, paratacamite and botallackite. Mineralogical Magazine, 53 (373) 557-563 doi:10.1180/minmag.1989.053.373.06
Hughes, John M., Bloodaxe, Erich S., Kobel, Kyle D., Drexler, John W. (1996) The atomic arrangement of ojuelaite, ZnFe23+(AsO4)2(OH)2·4H2O. Mineralogical Magazine, 60 (400) 519-521 doi:10.1180/minmag.1996.060.400.15
Howie, R. A. (1996) D. Viner, The Iona Marble Quarry. Inverness (New Iona Press) 1992, 24 pp. Price £3.95 (+ £0.50 p & p) ISBN 0-9516283-2-1. Mineralogical Magazine, 60 (400) 540 doi:10.1180/minmag.1996.060.400.21
Alun Humphreys, D., Thomas, John H., Williams, Peter A., Symes, Robert F. (1980) The chemical stability of mendipite, diaboleïte, chloroxiphite, and cumengéite, and their relationships to other secondary lead(II) minerals. Mineralogical Magazine, 43 (331) 901-904 doi:10.1180/minmag.1980.043.331.13
Solly, R. H. (1891) Cassiterite, “Sparable Tin,” from Cornwall. Mineralogical Magazine and Journal of the Mineralogical Society, 9 (43) 199-208 doi:10.1180/minmag.1891.009.43.01
Springer, G. (1968) Electronprobe analyses of stannite and related tin minerals. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (284) 1045-1051 doi:10.1180/minmag.1968.036.284.02
 
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