| Reference Type | Journal (article/letter/editorial) |
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| Title | Di-μ2-methanolato-bis[tetrakis(pyrimidin-2-amine-κN
1)cobalt(II)] bis(tetrafluoroborate) |
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| Journal | Acta Crystallographica Section E Structure Reports Online |
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| Authors | Li, Yang | Author |
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| Zhang, Xi-Quan | Author |
| Zhang, Xi-Chang | Author |
| Wang, Xiang-Jian | Author |
| Fang, Rui-Qin | Author |
| Year | 2006 (May 1) | Volume | 62 |
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| Issue | 5 |
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| Publisher | International Union of Crystallography (IUCr) |
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| DOI | doi:10.1107/s1600536806014036Search in ResearchGate |
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| Generate Citation Formats |
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| Mindat Ref. ID | 461128 | Long-form Identifier | mindat:1:5:461128:2 |
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| GUID | 0 |
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| Full Reference | Li, Yang, Zhang, Xi-Quan, Zhang, Xi-Chang, Wang, Xiang-Jian, Fang, Rui-Qin (2006) Di-μ2-methanolato-bis[tetrakis(pyrimidin-2-amine-κN
1)cobalt(II)] bis(tetrafluoroborate) Acta Crystallographica Section E Structure Reports Online, 62 (5) doi:10.1107/s1600536806014036 |
|---|
| Plain Text | Li, Yang, Zhang, Xi-Quan, Zhang, Xi-Chang, Wang, Xiang-Jian, Fang, Rui-Qin (2006) Di-μ2-methanolato-bis[tetrakis(pyrimidin-2-amine-κN
1)cobalt(II)] bis(tetrafluoroborate) Acta Crystallographica Section E Structure Reports Online, 62 (5) doi:10.1107/s1600536806014036 |
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| In | (2006, May) Acta Crystallographica Section E Structure Reports Online Vol. 62 (5) International Union of Crystallography (IUCr) |
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| Abstract/Notes | The title compound, [Co2(CH3O)2(C4H5N3)4](BF4)2, consists of a discrete dimeric CoII complex. The asymmetric unit consists of one pyrimidin-2-amine ligand, which occupies a general position, and one methanolate group, as well as one CoII cation and one tetrafluoroborate anion, which are located in special positions. The CoII cation lies on a twofold rotation axis, whereas the tetrafluoroborate anion and the methanolate group lie on mirror planes. The N atoms of the pyrimidin-2-amine ligand are involved in intermolecular hydrogen bonding. From this arrangement, large channels are formed, which elongate in the direction of the crystallographic c axis. |
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