Zheng, Xianfu, Niu, Caoyuan, Wan, Xinsheng, Kou, Chunhong (2007) Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(hexafluoridophosphate) monohydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807048209
Reference Type | Journal (article/letter/editorial) | ||
---|---|---|---|
Title | Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(hexafluoridophosphate) monohydrate | ||
Journal | Acta Crystallographica Section E Structure Reports Online | ||
Authors | Zheng, Xianfu | Author | |
Niu, Caoyuan | Author | ||
Wan, Xinsheng | Author | ||
Kou, Chunhong | Author | ||
Year | 2007 (November 1) | Volume | 63 |
Issue | 11 | ||
Publisher | International Union of Crystallography (IUCr) | ||
DOI | doi:10.1107/s1600536807048209Search in ResearchGate | ||
Generate Citation Formats | |||
Mindat Ref. ID | 466862 | Long-form Identifier | mindat:1:5:466862:0 |
GUID | 0 | ||
Full Reference | Zheng, Xianfu, Niu, Caoyuan, Wan, Xinsheng, Kou, Chunhong (2007) Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(hexafluoridophosphate) monohydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807048209 | ||
Plain Text | Zheng, Xianfu, Niu, Caoyuan, Wan, Xinsheng, Kou, Chunhong (2007) Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(hexafluoridophosphate) monohydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807048209 | ||
In | (2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr) | ||
Abstract/Notes | The title mononuclear MnII complex, [Mn(C13H14N2)4(H2O)2](PF6)2·H2O, is isostructural with the previously reported ZnII complex. The metal center is coordinated by four monodentate 1,3-di-4-pyridylpropane (L1) ligands and two water molecules. One L1 ligand is affected by disorder of two propane C atoms, which are distributed over two positions, with occupancies 0.771 (8)/0.229 (8). The asymmetric unit is completed by one solvent water molecule and two PF6 − anions, both disordered over two positions, with occupancies for F atoms of 0.621 (10)/0.379 (10) for one anion and 0.69 (2)/0.31 (2) for the other. Uncoordinated N atoms of pyridyl groups belonging to L1 and water molecules are involved in hydrogen bonds, with D...A separations ranging from 1.85 (4) to 2.07 (4) Å and D—H...A angles from 169 (3) to 174 (4)°. |
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