Reference Type | Journal (article/letter/editorial) |
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Title | Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate |
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Journal | Acta Crystallographica Section E Structure Reports Online |
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Authors | Qiu, Yu-E | Author |
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Year | 2007 (November 1) | Volume | 63 |
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Issue | 11 |
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Publisher | International Union of Crystallography (IUCr) |
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DOI | doi:10.1107/s1600536807052580Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 467815 | Long-form Identifier | mindat:1:5:467815:5 |
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GUID | 0 |
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Full Reference | Qiu, Yu-E (2007) Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052580 |
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Plain Text | Qiu, Yu-E (2007) Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052580 |
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In | (2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr) |
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Abstract/Notes | The title compound, [ZnCl2(C26H20N2)]·0.35H2O, consists of one mononuclear dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) molecule and a partial-occupancy water molecule. The ZnII atom is coordinated by two N atoms of one phenanthroline molecule and two chloride ions in a tetrahedral geometry. In the structure there exist O—H...Cl hydrogen bonds and π–π interactions [centroid–centroid = 4.035 (4) Å and vertical distance = 3.883 (4) Å], which lead to the formation of one-dimensional supramolecular chains. This compound is isostructural with the CuCl2, NiI2, NiBr2 and PtI2 adducts of the ligand 9-dimethyl-4,7-diphenyl-1,10-phenanthroline. |
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