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Qiu, Yu-E (2007) Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052580

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Reference TypeJournal (article/letter/editorial)
TitleDichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate
JournalActa Crystallographica Section E Structure Reports Online
AuthorsQiu, Yu-EAuthor
Year2007 (November 1)Volume63
Issue11
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s1600536807052580Search in ResearchGate
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Mindat Ref. ID467815Long-form Identifiermindat:1:5:467815:5
GUID0
Full ReferenceQiu, Yu-E (2007) Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052580
Plain TextQiu, Yu-E (2007) Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052580
In(2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr)
Abstract/NotesThe title compound, [ZnCl2(C26H20N2)]·0.35H2O, consists of one mononuclear dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) molecule and a partial-occupancy water molecule. The ZnII atom is coordinated by two N atoms of one phenanthroline molecule and two chloride ions in a tetrahedral geometry. In the structure there exist O—H...Cl hydrogen bonds and π–π interactions [centroid–centroid = 4.035 (4) Å and vertical distance = 3.883 (4) Å], which lead to the formation of one-dimensional supramolecular chains. This compound is isostructural with the CuCl2, NiI2, NiBr2 and PtI2 adducts of the ligand 9-dimethyl-4,7-diphenyl-1,10-phenanthroline.


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