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McConnell, J. D. C., McKie, Duncan (1960) The kinetics of the ordering process in triclinic NaAlSi3O8. Mineralogical Magazine and Journal of the Mineralogical Society, 32 (249) 436-454 doi:10.1180/minmag.1960.032.249.03

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Reference TypeJournal (article/letter/editorial)
TitleThe kinetics of the ordering process in triclinic NaAlSi3O8
JournalMineralogical Magazine and Journal of the Mineralogical Society
AuthorsMcConnell, J. D. C.Author
McKie, DuncanAuthor
Year1960 (June)Volume32
Issue249
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_32/32-249-436.pdf+
DOIdoi:10.1180/minmag.1960.032.249.03
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Mindat Ref. ID5563Long-form Identifiermindat:1:5:5563:9
GUID0
Full ReferenceMcConnell, J. D. C., McKie, Duncan (1960) The kinetics of the ordering process in triclinic NaAlSi3O8. Mineralogical Magazine and Journal of the Mineralogical Society, 32 (249) 436-454 doi:10.1180/minmag.1960.032.249.03
Plain TextMcConnell, J. D. C., McKie, Duncan (1960) The kinetics of the ordering process in triclinic NaAlSi3O8. Mineralogical Magazine and Journal of the Mineralogical Society, 32 (249) 436-454 doi:10.1180/minmag.1960.032.249.03
In(1959) Mineralogical Magazine Vol. 32 (249) Mineralogical Society
Abstract/NotesSummaryA kinetic analysis is presented of the data of MacKenzie (1957) on the hydrothermal treatment of NaAlSi3O8 under isobaric, isothermal conditions in the temperature range 450° C. to 1000° C.The analysis indicates the existence of a smeared polymorphic transformation in the temperature range around 600° C. The activation energy for the transformation is about 60 kcal. mole−1 and has been equated with the process of self-diffusion involved in Al-Si ordering in the structure. Some dry-heating experiments and the influence of varying water vapour pressure are discussed.


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