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Fraser, W. E., Downie, G. (1964) The spectrochemical determination of feldspars within the field microcline-albite—labradorite. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (264) 790-798 doi:10.1180/minmag.1964.033.264.07

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Reference TypeJournal (article/letter/editorial)
TitleThe spectrochemical determination of feldspars within the field microcline-albite—labradorite
JournalMineralogical Magazine and Journal of the Mineralogical Society
AuthorsFraser, W. E.Author
Downie, G.Author
Year1964 (March)Volume33
Issue264
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_33/33-264-790.pdf+
DOIdoi:10.1180/minmag.1964.033.264.07Search in ResearchGate
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Mindat Ref. ID5784Long-form Identifiermindat:1:5:5784:8
GUID0
Full ReferenceFraser, W. E., Downie, G. (1964) The spectrochemical determination of feldspars within the field microcline-albite—labradorite. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (264) 790-798 doi:10.1180/minmag.1964.033.264.07
Plain TextFraser, W. E., Downie, G. (1964) The spectrochemical determination of feldspars within the field microcline-albite—labradorite. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (264) 790-798 doi:10.1180/minmag.1964.033.264.07
In(1962) Mineralogical Magazine Vol. 33 (264) Mineralogical Society
Abstract/NotesSummaryTwo spectrochemical methods of feldspar determination are described: one based on the flame spectrophotometer; the other on the quartz spectrograph. For the first method, unknown feldspars are dissolved in a mixture of hydrofluoric and perchloric acids and diluted to 1 : 104. Percentages of Or and An are determined by comparison with dissolved feldspar standards at the same dilution; percentages of Ab are estimated by difference. For the second method, unknown feldspars are burned, unadulterated, in the cathode of the spectrograph arc and a visual estimation is made of the intensities of the following lines: Na5688, Na5683, Ca4455, Ca4435, Ca4425, K4047, K4044, Ca3644, K3447, Na3303, Na3302, and Ca3159. The estimated intensities are then substituted in two empirically determined functions:(ICa4455+ICa4435+ICa4255+ICa3644+ICa3159)−4/3(INa5688+INa5683+INa3303+INa3302)and (3INa5688+3INa5683+2INa3303+INa3302)−43(4IK4047+3IK4044+2IK3447) .From the algebraic values of these two functions, the compositions of the unknown feldspars, expressed as percentages of Or, Ab, and An, are read directly from a chart based on results obtained from feldspar standards of known chemical composition.


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