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Chang, Luke L. Y. (1968) Subsolidus phase relations in the system ZnWO4-ZnMoO4-MnWO4-MnMoO4. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (283) 992-996 doi:10.1180/minmag.1968.283.036.11

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Reference TypeJournal (article/letter/editorial)
TitleSubsolidus phase relations in the system ZnWO4-ZnMoO4-MnWO4-MnMoO4
JournalMineralogical Magazine and Journal of the Mineralogical Society
AuthorsChang, Luke L. Y.Author
Year1968 (September)Volume36
Issue283
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_36/36-283-992.pdf+
DOIdoi:10.1180/minmag.1968.283.036.11Search in ResearchGate
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Mindat Ref. ID6192Long-form Identifiermindat:1:5:6192:0
GUID0
Full ReferenceChang, Luke L. Y. (1968) Subsolidus phase relations in the system ZnWO4-ZnMoO4-MnWO4-MnMoO4. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (283) 992-996 doi:10.1180/minmag.1968.283.036.11
Plain TextChang, Luke L. Y. (1968) Subsolidus phase relations in the system ZnWO4-ZnMoO4-MnWO4-MnMoO4. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (283) 992-996 doi:10.1180/minmag.1968.283.036.11
In(1966) Mineralogical Magazine Vol. 36 (283) Mineralogical Society
Abstract/NotesSummarySubsolidus phase relations in the systems ZnWO4-MnWO4, ZnWO4-ZnMoO4, MnMoO4-ZnMoO4, and MnWO4-MnMoO4, were investigated by using the quenching technique. A complete series of solid solutions forms in the system ZnWO4-MnWO4 above 840° C, whereas limited solid solubilities were found in the other three. The various limits of solubility are, at 620° C, 4·0 mole % ZnMoO4 in ZnWO4 and 4·0 mole % ZnWO4 in ZnMoO4, 13·0 mole % ZnMoO4 in MnMoO4 and 12·0 mole % MnMoO4 in ZnMoO4, 9·0 mole % MnMoO4 in MnWO4 and 6·0 mole % in MnWO4 in MnMoO4; and at 1000° C, 15·0 mole % ZnMoO4 in ZnWO4 and 15·0 mole % ZnWO4 in ZnMoO4, 36·0 mole % ZnMoO4 in MnMoO4 and 29·0 mole % MnMoO4 in ZnMoO4, 15·0 mole % MnMoO4 in MnWO4 and 27·0 mole % MnWO4 in MnMoO4.Subsolidus phase relations in the system ZnWO4-ZnMoO4-MnWO4-MnMoO4 were studied at 900° C. The solubility of molybdenum in the (Zn,Mn)WO4 series increases from both end members to a maximum of 27·0 mole % at the composition Mn35Zn65. Both molybdates also have limited ranges of solid solutions, and a three-phase region occupies the central portion of the system defined by three points with compositions of 41 mole % ZnMoO4, 26 mole % MnMoO4, 33 mole % MnWO4; 57 mole % ZnMoO4, 10 mole % MnMoO4, 35 mole % MnWO4; and 27 mole % ZnMoO4, 34 mole % MnWO4, 39 mole % ZnWO4.


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