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Gadolinite-(Ce)

A valid IMA mineral species
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About Gadolinite-(Ce)Hide

04751420017271923338453.jpg
Johan Gadolin
Formula:
(Ce,La,Nd,Y)2Fe2+Be2Si2O10
Often slightly radioactive due to minor U and/or Th contents; therefore often metamict.
Colour:
Black
Lustre:
Vitreous
Hardness:
6½ - 7
Specific Gravity:
4.20
Crystal System:
Monoclinic
Name:
Named for its relationship to gadolinite-(Y), but with cerium as the dominant rare earth element. Gadolinite honors Johan Gadolin (5 June 1760, Turku, Finland - 15 August 1852, Mynämäki, Finland), chemist, physicist, and mineralogist.

The cerium analogue of Gadolinite-(Y) and Gadolinite-(Nd).
At the type locality, gadolinite-(Ce) often occurs with an orange or yellow alteration rim (up to 0.5 mm).

The Italian occurrences of gadolinite-(Ce) are not probed by analyses and most correctly they should be classified as "gadolinite" (s.l.).


Unique IdentifiersHide

Mindat ID:
1627
Long-form identifier:
mindat:1:1:1627:4

IMA Classification of Gadolinite-(Ce)Hide

Approved
IMA Formula:
Ce2Fe2+Be2O2(SiO4)2
Approval year:
1987
First published:
1978

Classification of Gadolinite-(Ce)Hide

9.AJ.20

9 : SILICATES (Germanates)
A : Nesosilicates
J : Nesosilicates with BO3 triangles and/or B[4], Be[4] tetrahedra, cornersharing with SiO4
54.2.1b.2

54 : NESOSILICATES Borosilicates and Some Beryllosilicates
2 : Borosilicates and Some Beryllosilicates with B in [4] coordination
14.3.24

14 : Silicates not Containing Aluminum
3 : Silicates of Be

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
Gad-CeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
GadSiivolam & Schmid (2007)Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download

Physical Properties of Gadolinite-(Ce)Hide

Vitreous
Colour:
Black
Comment:
Olive green in thin sections
Hardness:
6½ - 7 on Mohs scale
Fracture:
Conchoidal
Density:
4.20 g/cm3 (Measured)    

Optical Data of Gadolinite-(Ce)Hide

Type:
Biaxial (-)
RI values:
nα = 1.780 nβ = 1.800 nγ = 1.810
2V:
Measured: 70° (5)
Birefringence:
mid-2nd order birefringence
Max. Birefringence:
δ = 0.030
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Pleochroism:
Non-pleochroic
Comments:
pale yellow-green in thin section
Comments:
The mineral is reported in numerous sources as "isotropic" with n = 1.78, but as the mineral is monoclinic, this observation was clearly done on metamict material. This assertion appears to derive from an observation on material only from Skien, Norway (Segalstad & Larsen, 1978). In contrast to the Norwegian sample, gadolinite-(Ce) from the Malmkärra mine, Norberg, Sweden is U-free and Th-free and is non-metamict. This material shows normal anisotropic optical properties consistent with a monoclinic symmetry (non-zero birefringence; biaxial nature).

Note that in the absence of measured R.I. data for anisotropic gadolinite-(Ce), the listed R.I. values above are those of the analogous species gadolinite-(Nd) (but no estimate of errors is attempted). However, these values nonetheless successfully reproduce the observed birefringence and 2V° of the Malmkärra mine gadolinite-(Ce). Not unexpectedly, the overall optical properties of non-metamict gadolinite-(Ce) appear to be largely comparable to those of gadolinite-(Nd).

Chemistry of Gadolinite-(Ce)Hide

Mindat Formula:
(Ce,La,Nd,Y)2Fe2+Be2Si2O10

Often slightly radioactive due to minor U and/or Th contents; therefore often metamict.
Element Weights:
Element% weight
Ce49.141 %
O28.056 %
Si9.850 %
Fe9.793 %
Be3.161 %

Calculated from ideal end-member formula.

Crystallography of Gadolinite-(Ce)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 9.8973 Å, b = 7.6282 Å, c = 4.7505 Å
β = 90.416°
Ratio:
a:b:c = 1.297 : 1 : 0.623
Unit Cell V:
358.65 ų (Calculated from Unit Cell)
Comment:
Space group P2/c was determined for material heated at 700oC

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.06 Å(42)
3.74 Å(37)
3.44 Å(34)
3.13 Å(86)
2.85 Å(100)
2.56 Å(46)
2.21 Å(33)
1.976 Å(30)
Comments:
Spacings for the material hydrothermally recrystallized at 700oC: 2.88 (100), 4.81 (90), 2.60 (80), 2.59 (80), 3.18 (70), 3.00 (70), and 3.59 (60)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of Gadolinite-(Ce)Hide

General Appearance of Type Material:
Black irregular masses up to 20 mm in matrix.
Place of Conservation of Type Material:
Mineralogical-Geological Museum, University of Oslo, Oslo, Norway, number 21325.
Chemical Analysis of Type Material:
SiO222.99 %
BeO8.83 %
Al2O30.02 %
B2O30.55 %
TiO20.25 %
FeO10.65 %
MnO1.89 %
MgO0.33 %
CaO2.15 %
Na2O0.11 %
K2O0.52 %
Y2O314.82 %
La2O39.07 %
Ce2O315.55 %
Total:87.73 %
Geological Setting of Type Material:
Syenite pegmatite.
Associated Minerals at Type Locality:

Synonyms of Gadolinite-(Ce)Hide

Gadolinite (in part)

Other Language Names for Gadolinite-(Ce)Hide

Simplified Chinese:硅铍铈矿
Traditional Chinese:矽鈹鈰礦

Relationship of Gadolinite-(Ce) to other SpeciesHide

Other Members of Gadolinite Subgroup:
Calcybeborosilite-(Y)(Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2Mon.
Gadolinite-(Nd)Nd2Fe2+Be2O2(SiO4)2Mon. 2/m : P21/b
Gadolinite-(Y)Y2Fe2+Be2Si2O10Mon. 2/m : P21/b
Hingganite-(Ce)(Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
Hingganite-(Nd)Nd2◻Be2Si2O8(OH)2Mon. 2/m : P21/b
Hingganite-(Y)(Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
Hingganite-(Yb)(Yb,Y,REE)2◻Be2[SiO4]2(OH)2Mon. 2/m : P21/b
Minasgeraisite-(Y)(Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4Tric. 1 : P1
Unnamed (OH-analogue of Gadolinite-(Y))(Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2Mon. 2/m

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Gadolinite-(Ce) associated with AlbiteNa(AlSi3O8)
4 photos of Gadolinite-(Ce) associated with MicroclineK(AlSi3O8)
4 photos of Gadolinite-(Ce) associated with QuartzSiO2
4 photos of Gadolinite-(Ce) associated with PhenakiteBe2SiO4
2 photos of Gadolinite-(Ce) associated with AnniteKFe2+3(AlSi3O10)(OH)2
2 photos of Gadolinite-(Ce) associated with FluoriteCaF2
2 photos of Gadolinite-(Ce) associated with ThoriteTh(SiO4)
2 photos of Gadolinite-(Ce) associated with Xenotime-(Y)Y(PO4)
2 photos of Gadolinite-(Ce) associated with AdulariaKAlSi3O8
2 photos of Gadolinite-(Ce) associated with Monazite-(Ce)Ce(PO4)

Related Minerals - Strunz-mindat GroupingHide

9.AJ.Hingganite-(Nd)Nd2◻Be2Si2O8(OH)2Mon. 2/m : P21/b
9.AJ.Arrheniusite-(Ce)CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11Trig. 3m : R3m
9.AJ.05Ominelite(Fe2+,Mg)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm (2/m 2/m 2/m)
9.AJ.05Grandidierite(Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm (2/m 2/m 2/m)
9.AJ.10DumortieriteAl(Al2O)(Al2O)2(SiO4)3(BO3)Orth. mmm (2/m 2/m 2/m)
9.AJ.10Nioboholtite(Nb0.60.4)Al6BSi3O18Orth. mmm (2/m 2/m 2/m) : Pbcm
9.AJ.10Titanoholtite(Ti0.750.25)Al6BSi3O18Orth. mmm (2/m 2/m 2/m) : Pbcm
9.AJ.10Holtite(Ta0.60.4)Al6BSi3O18(O,OH)2.25Orth. mmm (2/m 2/m 2/m) : Pnma
9.AJ.10MagnesiodumortieriteMg(Al2OH)(Al2O)2(SiO4)3(BO3)Orth. mmm (2/m 2/m 2/m)
9.AJ.15GarrelsiteBa3NaSi2B7O16(OH)4Mon. 2/m : B2/b
9.AJ.20Muromontitenear Be2FeY2Si3O12
9.AJ.20Gadolinite-(Nd)Nd2Fe2+Be2O2(SiO4)2Mon. 2/m : P21/b
9.AJ.20DatoliteCaB(SiO4)(OH)Mon. 2/m : P21/b
9.AJ.20Melanocerite-(Ce)(Ce,Ca)5(SiO4,BO4)3(OH,O)Hex.
9.AJ.20Gadolinite-(Y)Y2Fe2+Be2Si2O10Mon. 2/m : P21/b
9.AJ.20Unnamed (OH-analogue of Gadolinite-(Y))(Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2Mon. 2/m
9.AJ.20Hingganite-(Ce)(Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Y)(Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Yb)(Yb,Y,REE)2◻Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20HomiliteCa2(Fe2+,Mg)B2Si2O10Mon. 2/m : P21/b
9.AJ.20Minasgeraisite-(Y)(Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4Tric. 1 : P1
9.AJ.20Calcybeborosilite-(Y)(Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2Mon.
9.AJ.25Stillwellite-(La)LaBSiO5Trig. 3 2 : P32 2 1
9.AJ.25Stillwellite-(Ce)(Ce,La,Ca)BSiO5Trig. 3 : P31
9.AJ.30Cappelenite-(Y)Ba(Y,Ce)6Si3B6O24F2Trig. 3 : P3
9.AJ.35Laptevite-(Ce)Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11Trig. 3m : R3m
9.AJ.35Proshchenkoite-(Y)Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14Trig. 3m : R3m
9.AJ.35Okanoganite-(Y)(Na,Ca)3(Y,Ce)12Si6B2O27F14Trig. 3m : R3m
9.AJ.35Hundholmenite-(Y)(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48Trig. 3m : R3m
9.AJ.35Vicanite-(Ce)(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7Trig. 3m : R3m
9.AJ.40JadariteLiNaSiB3O7(OH)Mon. 2/m

Other InformationHide

Thermal Behaviour:
DTA shows a broad and indistinct exotherm at about 250-350 °C and a large exotherm at 790 °C grading into a smaller exotherm at 8l0 °C.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Gadolinite-(Ce)Hide

References for Gadolinite-(Ce)Hide

Localities for Gadolinite-(Ce)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Salzburg
    • St. Johann im Pongau District
      • Bad Gastein
        • Böckstein
Wittern (1994)
    • Zell am See District
      • Bramberg am Wildkogel
        • Nasenkopf mountain
          • Leckbachgraben
Exel (1993)
Germany
 
  • Lower Saxony
    • Goslar District
      • Bad Harzburg
        • Radau valley
Italy
 
  • Lazio
    • Metropolitan City of Rome Capital
      • Campagnano di Roma
Thorne (n.d.)
    • Viterbo Province
Carlini
  • Piedmont
    • Verbano-Cusio-Ossola Province
      • Baveno
        • Oltrefiume
          • Mount Camoscio
Grill (1935)
Pezzotta et al. (1999)
  • Trentino-Alto Adige (Trentino-South Tyrol)
    • South Tyrol
      • Wipptal (Alta Vall'Isarco)
        • Pfitsch (Val di Vizze)
          • Sankt Jakob (San Giacomo)
            • Vizze Pass (Pfitsch Pass; Pfitscher Joch)
Folie et al. (2010)
Mozambique
 
  • Zambezia Province
Behier (1957) +1 other reference
Norway
 
  • Telemark
    • Porsgrunn
      • Auenlandet
Larsen et al. (2010)
      • Bjørkedalen
Segalstad et al. (1978)
- (n.d.)
      • Langangen
        • Kokkersvold - Blåfjell E18 roadcuts
Larsen et al. (1981, June) +1 other reference
Raade et al. (1983)
Grice et al. (2013)
  • Vestfold
    • Larvik Commune
      • Hedrum
        • Lågendalen
Larsen et al. (1992)
      • Malerød
Andresen (2011)
Larsen et al. (2010)
      • Tjølling
        • Håkestad
Engvoldsen et al. (1991)
        • Klåstad
Hansen (1981) +1 other reference
Berge (n.d.)
        • Stålaker
Engvoldsen et al. (1991)
      • Tvedalen
Engvoldsen et al. (1991)
Engvoldsen et al. (1991)
Collection of Peter Andresen.
Berge (1993) +1 other reference
Engvoldsen et al. (1991)
Andresen (2013)
Larsen et al. (1981, June) +1 other reference
Pakistan
 
  • Khyber Pakhtunkhwa Province
    • Peshawar District
      • Hameed Abad Kafoor Dheri
RUFF
Poland
 
  • Lower Silesian Voivodeship
    • Karkonosze County
      • Szklarska Poręba
Evans et al. (2018)
Russia
 
  • Chelyabinsk Oblast
    • Kyshtym
Kasatkin et al. (2020)
  • Murmansk Oblast
...
      • Kukisvumchorr Mt
        • East slope
European Journal of Mineralogy 19 (2007)
Sweden
 
  • Västmanland County
    • Norberg
Nysten et al. (2006)
Nysten et al. (2006) +1 other reference
Andersson et al. (2024)
      • Röberg ore field
Nysten et al. (2006)
    • Skinnskatteberg
      • Riddarhyttan
Öhman et al. (2005) +1 other reference
Andersson et al. (2024)
USA
 
  • Colorado
    • Jefferson County
      • Clear Creek pegmatite Province
Hanley et al. (1950) +1 other reference
      • South Platte Pegmatite Mining District
Eckel et al. (1997)
Eckel et al. (1997)
Ream (2004)
  • New Hampshire
    • Grafton County
      • Bethlehem
Smith (2005) +1 other reference
  • Washington
    • Okanogan County
      • Golden Horn Batholith
Metamict crystal identified by XRD after annealing at 700° for 48 hours by John Attard et al. (Ce)
 
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