Reference Type | Journal (article/letter/editorial) |
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Title | Berndlehmannite: A new V-bearing sulfide mineral from the black shale-hosted Zhongcun vanadium deposit, South China |
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Journal | American Mineralogist |
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Authors | Fu, Xuerui | Author |
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Li, Guowu | Author |
Xu, Lingang | Author |
Xue, Yuan | Author |
Sun, Ningyue | Author |
Hao, Jinhua | Author |
Jian, Wei | Author |
Yan, Hao | Author |
Ye, Huishou | Author |
Ding, Jianhua | Author |
Yuan, Peng | Author |
Year | 2025 (January) |
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URL | |
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DOI | doi:10.2138/am-2024-9541Search in ResearchGate |
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Classification | Not set | LoC | Not set |
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Mindat Ref. ID | 17970293 | Long-form Identifier | mindat:1:5:17970293:8 |
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GUID | 0 |
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Full Reference | Fu, Xuerui, Li, Guowu, Xu, Lingang, Xue, Yuan, Sun, Ningyue, Hao, Jinhua, Jian, Wei, Yan, Hao, Ye, Huishou, Ding, Jianhua, et al. (2025) Berndlehmannite: A new V-bearing sulfide mineral from the black shale-hosted Zhongcun vanadium deposit, South China. American Mineralogist. doi:10.2138/am-2024-9541 |
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Plain Text | Fu, Xuerui, Li, Guowu, Xu, Lingang, Xue, Yuan, Sun, Ningyue, Hao, Jinhua, Jian, Wei, Yan, Hao, Ye, Huishou, Ding, Jianhua, et al. (2025) Berndlehmannite: A new V-bearing sulfide mineral from the black shale-hosted Zhongcun vanadium deposit, South China. American Mineralogist. doi:10.2138/am-2024-9541 |
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In | Link this record to the correct parent record (if possible) |
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Abstract/Notes | Berndlehmannite, Cu(CrV)S4, is a newly identified V-bearing sulfide mineral discovered in the black shale-hosted Zhongcun vanadium deposit, South China. It is abundant in a phosphatic nodule-rich layer and is commonly mineralogically associated with roscoelite, quartz, and framboidal pyrite. Berndlehmannite exhibits black color in hand specimens with a black streak and it comprises subhedral grains that vary in size from 20 to 120 μm. The mineral is opaque with a cream-colored polished surface under reflected light. It has a Mohs hardness of 3½ with a {111} perfect cleavage, and its calculated density is 4.17 g·cm−3. Berndlehmannite is cubic, with space group Fd-3m; the unit-cell parameters determined from powder data are a = 9.8585(22) Å, V = 958.1(6) Å3, and Z = 8. The unit-cell parameters by single-crystal X-ray diffraction are a = 9.8374(2) Å, V = 952.01(6) Å3, Z = 8, and the final value of R is 0.015. The mineral is a member of the carrollite subgroup within the thiospinel group, featuring (Cr,V)S6 in octahedral coordination and CuS4 in tetrahedral coordination. The calculated empirical formula from electron-probe microanalysis is (Cu+0.99Zn0.02)Σ1.01(Cr3+0.87V4+1.00Sb0.07As0.04)Σ1.98S4.01 with an average V content of 17.0 wt%. It has the highest V component compared to other V-bearing minerals in black shales and may provide new insight into the vanadium enrichment mechanism in black shales. Berndlehmannite is named to honor Bernd Lehmann (1950- ), Professor emeritus of Economic Geology at Technische Universität Clausthal, Germany. |
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