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Huang, Xiao-Hui (2013) A three-dimensional manganese(II) metal–organic framework based on 5-methoxybenzene-1,3-dicarboxylic acid and exhibiting a pts net. Acta Crystallographica Section C Crystal Structure Communications, 69 (5) 483-485 doi:10.1107/s0108270113008512

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Reference TypeJournal (article/letter/editorial)
TitleA three-dimensional manganese(II) metal–organic framework based on 5-methoxybenzene-1,3-dicarboxylic acid and exhibiting a pts net
JournalActa Crystallographica Section C Crystal Structure Communications
AuthorsHuang, Xiao-HuiAuthor
Year2013 (May 15)Volume69
Issue5
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s0108270113008512Search in ResearchGate
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Mindat Ref. ID191105Long-form Identifiermindat:1:5:191105:7
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Full ReferenceHuang, Xiao-Hui (2013) A three-dimensional manganese(II) metal–organic framework based on 5-methoxybenzene-1,3-dicarboxylic acid and exhibiting a pts net. Acta Crystallographica Section C Crystal Structure Communications, 69 (5) 483-485 doi:10.1107/s0108270113008512
Plain TextHuang, Xiao-Hui (2013) A three-dimensional manganese(II) metal–organic framework based on 5-methoxybenzene-1,3-dicarboxylic acid and exhibiting a pts net. Acta Crystallographica Section C Crystal Structure Communications, 69 (5) 483-485 doi:10.1107/s0108270113008512
In(2013, May) Acta Crystallographica Section C Crystal Structure Communications Vol. 69 (5) International Union of Crystallography (IUCr)
Abstract/NotesThe solvothermal reaction of MnCl2·H2O and 5-methoxybenzene-1,3-dicarboxylic acid (MeO-m-H2BDC) led to a three-dimensional MnIImetal–organic framework, namely poly[(dimethylformamide-κO)(μ4-5-methoxybenzene-1,3-dicarboxylato-κ4O1:O1′:O3,O3′:O3)manganese(II)], [Mn(C9H6O5)(C3H7NO)]nor [Mn(MeO-m-BDC)(DMF)]n(DMF is dimethylformamide). The MnIIatom is six-coordinated and exhibits a distorted octahedral geometry formed by five carboxylate O atoms from four different MeO-m-BDC2−anionic ligands and by one DMF O atom. The three-dimensional framework of (I) formed by the bridging MeO-m-BDC2−ligands and the MnIIatoms exhibits aptstopological network when MeO-m-BDC2−and MnIIare viewed as four-connected nodes.


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