Deng, Yong-Kai, Yan, Zhi-Hao, Sun, Di (2013) A one-dimensional cadmium metal–organic chain based on a [Cd4(COO)4] secondary building unit and a flexible dicarboxylic acid ligand. Acta Crystallographica Section C Crystal Structure Communications, 69 (10) 1147-1151 doi:10.1107/s0108270113025699
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | A one-dimensional cadmium metal–organic chain based on a [Cd4(COO)4] secondary building unit and a flexible dicarboxylic acid ligand | ||
| Journal | Acta Crystallographica Section C Crystal Structure Communications | ||
| Authors | Deng, Yong-Kai | Author | |
| Yan, Zhi-Hao | Author | ||
| Sun, Di | Author | ||
| Year | 2013 (October 1) | Volume | 69 |
| Issue | 10 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s0108270113025699Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 191308 | Long-form Identifier | mindat:1:5:191308:2 |
| GUID | 0 | ||
| Full Reference | Deng, Yong-Kai, Yan, Zhi-Hao, Sun, Di (2013) A one-dimensional cadmium metal–organic chain based on a [Cd4(COO)4] secondary building unit and a flexible dicarboxylic acid ligand. Acta Crystallographica Section C Crystal Structure Communications, 69 (10) 1147-1151 doi:10.1107/s0108270113025699 | ||
| Plain Text | Deng, Yong-Kai, Yan, Zhi-Hao, Sun, Di (2013) A one-dimensional cadmium metal–organic chain based on a [Cd4(COO)4] secondary building unit and a flexible dicarboxylic acid ligand. Acta Crystallographica Section C Crystal Structure Communications, 69 (10) 1147-1151 doi:10.1107/s0108270113025699 | ||
| In | (2013, October) Acta Crystallographica Section C Crystal Structure Communications Vol. 69 (10) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | An infinite one-dimensional cadmium metal–organic chain, namelycatena-poly[aquabis(μ3-2,2′-{[1,2-phenylenebis(methylene)]bis(sulfanediyl)}dibenzoato)dicadmium(II)], [Cd2(C22H16O4S2)2(H2O)]n, was synthesized by solvothermal reaction of Cd(NO3)2·4H2O and 2,2′-{[1,2-phenylenebis(methylene)]bis(sulfanediyl)}dibenzoic acid (H2L). The CdIIcentres have six-coordinate CdS2O4and CdSO5geometries. Due to the flexible –CH2–S– arms, theL2−ligand adopts bothsynandanticonformations. Four CdIIcations are linked by twosyn L2−ligands to form a centrosymmetric planar tetranuclear CdIIcore, which is further extended through bonding to theanti L2−ligands to form a one-dimensional metal–organic chain. Adjacent one-dimensional chains are connected by C—H...π interactions and nonclassical C—H...O hydrogen bonds to form the resultant three-dimensional supramolecular framework. | ||
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