| Reference Type | Journal (article/letter/editorial) |
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| Title | trans-Dichlorobis[tris(4-fluorophenyl)phosphine]palladium(II) toluene solvate |
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| Journal | Acta Crystallographica Section E Structure Reports Online |
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| Authors | Meijboom, Reinout | Author |
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| Muller, Alfred | Author |
| Roodt, Andreas | Author |
| Janse van Rensburg, J. Marthinus | Author |
| Year | 2006 (April 1) | Volume | 62 |
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| Issue | 4 |
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| Publisher | International Union of Crystallography (IUCr) |
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| DOI | doi:10.1107/s1600536806010579Search in ResearchGate |
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| Generate Citation Formats |
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| Mindat Ref. ID | 460863 | Long-form Identifier | mindat:1:5:460863:3 |
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| GUID | 0 |
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| Full Reference | Meijboom, Reinout, Muller, Alfred, Roodt, Andreas, Janse van Rensburg, J. Marthinus (2006) trans-Dichlorobis[tris(4-fluorophenyl)phosphine]palladium(II) toluene solvate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010579 |
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| Plain Text | Meijboom, Reinout, Muller, Alfred, Roodt, Andreas, Janse van Rensburg, J. Marthinus (2006) trans-Dichlorobis[tris(4-fluorophenyl)phosphine]palladium(II) toluene solvate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010579 |
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| In | (2006, April) Acta Crystallographica Section E Structure Reports Online Vol. 62 (4) International Union of Crystallography (IUCr) |
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| Abstract/Notes | The title compound, trans-[PdCl2{P(C6H4F)3}2]·C7H8, where P(C6H4F)3 is tris(4-fluorophenyl)phosphine, crystallizes with both molecules in special positions. The trans-[PdCl2{P(C6H4F)3}2] molecule lies on an inversion centre, resulting in a distorted trans square-planar geometry. The Pd—P and Pd—Cl distances are 2.3398 (12) and 2.2955 (13) Å, respectively, and the P—Pd—Cl angle is 87.58 (5)°. The effective cone angle for the tris(4-fluorophenyl)phosphine group was calculated to be 152°. The toluene molecule lies on a twofold rotation axis. |
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