Reference Type | Journal (article/letter/editorial) |
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Title | trans-Bis(benzyldiphenylphosphine)carbonylchlororhodium(I) |
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Journal | Acta Crystallographica Section E Structure Reports Online |
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Authors | Meijboom, Reinout | Author |
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Muller, Alfred | Author |
Roodt, Andreas | Author |
Year | 2006 (April 1) | Volume | 62 |
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Issue | 4 |
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Publisher | International Union of Crystallography (IUCr) |
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DOI | doi:10.1107/s1600536806006076Search in ResearchGate |
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Mindat Ref. ID | 460603 | Long-form Identifier | mindat:1:5:460603:5 |
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GUID | 0 |
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Full Reference | Meijboom, Reinout, Muller, Alfred, Roodt, Andreas (2006) trans-Bis(benzyldiphenylphosphine)carbonylchlororhodium(I) Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806006076 |
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Plain Text | Meijboom, Reinout, Muller, Alfred, Roodt, Andreas (2006) trans-Bis(benzyldiphenylphosphine)carbonylchlororhodium(I) Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806006076 |
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In | (2006, April) Acta Crystallographica Section E Structure Reports Online Vol. 62 (4) International Union of Crystallography (IUCr) |
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Abstract/Notes | In the title compound, trans-[RhCl(C19H17P)2(CO)], selected geometrical parameters are: Rh—P = 2.3204 (5) and 2.3365 (5) Å, Rh—Cl = 2.3687 (5) Å and Rh—C = 1.8007 (15) Å, and P—Rh—P = 179.005 (16)°, P—Rh—Cl = 88.807 (15)° and 90.529 (15)°, and Rh—C[triple-bond]O = 176.43 (13)°. The effective cone angles for the phosphine ligands were calculated to be 156 and 160°. |
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