Reference Type | Journal (article/letter/editorial) |
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Title | Di-μ2-chloro-bis[(benzyldiphenylphosphine)chloropalladium(II)] |
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Journal | Acta Crystallographica Section E Structure Reports Online |
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Authors | Meijboom, Reinout | Author |
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Muller, Alfred | Author |
Roodt, Andreas | Author |
Year | 2006 (April 1) | Volume | 62 |
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Issue | 4 |
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Publisher | International Union of Crystallography (IUCr) |
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DOI | doi:10.1107/s1600536806010580Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 460864 | Long-form Identifier | mindat:1:5:460864:0 |
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GUID | 0 |
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Full Reference | Meijboom, Reinout, Muller, Alfred, Roodt, Andreas (2006) Di-μ2-chloro-bis[(benzyldiphenylphosphine)chloropalladium(II)]. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010580 |
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Plain Text | Meijboom, Reinout, Muller, Alfred, Roodt, Andreas (2006) Di-μ2-chloro-bis[(benzyldiphenylphosphine)chloropalladium(II)]. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010580 |
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In | (2006, April) Acta Crystallographica Section E Structure Reports Online Vol. 62 (4) International Union of Crystallography (IUCr) |
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Abstract/Notes | The molecule of the title compound, [Pd2Cl4(C19H17P)2] or [Pd(μ2-Cl)Cl(PPh2Bz)]2, where Bz = CH2Ph, lies on an inversion centre. The Pd atom has a distorted square-planar coordination environment formed by a benzyldiphenylphosphine [Pd—P = 2.2218 (6) Å], a terminal chloride [Pd—Cl = 2.2729 (5) Å] and two bridging chloride ligands. The Pd—Cl bond in the position trans to the phosphine ligand [Pd—Cl = 2.4123 (5) Å] is considerably longer than the Pd—Cl bond in the position trans to the terminal chloride [Pd—Cl = 2.3155 (5) Å]. |
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