Karupmøllerite-Ca
A valid IMA mineral species
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About Karupmøllerite-Ca
Formula:
(Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2O
Colour:
Grey-white to reddish-white
Lustre:
Vitreous, Dull
Hardness:
5
Specific Gravity:
2.71
Crystal System:
Monoclinic
Member of:
Name:
Named in honor of Sven Karup-Møller (b. 1936), mineralogist at the Technical University of Denmark, and discoverer of the mineral.
This page provides mineralogical data about Karupmøllerite-Ca.
Unique Identifiers
Mindat ID:
11159
Long-form identifier:
mindat:1:1:11159:7
IMA Classification of Karupmøllerite-Ca
Approved
Approval year:
2001
First published:
2002
Type description reference:
Pekov, I. V., Chukanov, N. V., Petersen, O. V., Zadov, A. E., Yamnova, N. A., Kabalov, Y. K., Schneider, J. (2002) Karupmøllerite–Ca, (Na,Ca,K)2Ca(Nb,Ti)4 (Si4O12)2(O,OH)4·7H2O, a new mineral of the labuntsovite group from
the Ilímaussaq alkaline complex, South Greenland. Neues Jahrbuch für Mineralogie - Monatshefte, 2002 (10) 433-444 doi:10.1127/0028-3649/2002/2002-0433
Classification of Karupmøllerite-Ca
9.CE.30c
9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Kmø-Ca | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Karupmøllerite-Ca
Vitreous, Dull
Transparency:
Translucent
Colour:
Grey-white to reddish-white
Streak:
White
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Density:
2.71 g/cm3 (Measured) 2.75 g/cm3 (Calculated)
Chemistry of Karupmøllerite-Ca
Mindat Formula:
(Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2O
Crystallography of Karupmøllerite-Ca
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 14.641(1) Å, b = 14.214(1) Å, c = 7.91(2) Å
β = 117.36(1)°
β = 117.36(1)°
Ratio:
a:b:c = 1.03 : 1 : 0.556
Unit Cell V:
1,461.99 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Pseudomorphs to 2 x 1.5 x 0.1 cm after lamellae of epistolite.
Twinning:
None observed.
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
7.104 Å | (73) |
7.026 Å | (100) |
6.482 Å | (45) |
4.996 Å | (74) |
3.253 Å | (38) |
3.250 Å | (36) |
3.242 Å | (34) |
3.171 Å | (56) |
3.150 Å | (38) |
Comments:
Mellemelv Stream Valley, Ilímaussaq complex, Greenland. The data are from Pekov et al. (2002).
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Karupmøllerite-Ca
General Appearance of Type Material:
Pseudomorphs after rectangular lamellae (up to 2 x 1.5 x 0.1 cm) of epistolite.
Place of Conservation of Type Material:
Fersman Mineralogical Museum, Moscow, Russia.
Geological Museum, Copenhagen, Denmark.
Geological Museum, Copenhagen, Denmark.
Geological Setting of Type Material:
In a naujaite pegmatite.
Associated Minerals at Type Locality:
Reference:
Pekov, I. V., Chukanov, N. V., Petersen, O. V., Zadov, A. E., Yamnova, N. A., Kabalov, Y. K., Schneider, J. (2002) Karupmøllerite–Ca, (Na,Ca,K)2Ca(Nb,Ti)4 (Si4O12)2(O,OH)4·7H2O, a new mineral of the labuntsovite group from
the Ilímaussaq alkaline complex, South Greenland. Neues Jahrbuch für Mineralogie - Monatshefte, 2002 (10) 433-444 doi:10.1127/0028-3649/2002/2002-0433
Synonyms of Karupmøllerite-Ca
Other Language Names for Karupmøllerite-Ca
Relationship of Karupmøllerite-Ca to other Species
Member of:
Other Members of Kuzmenkoite Group:
Burovaite-Ca | (Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2O | Mon. 2/m : B2/m |
Gjerdingenite-Ca | K2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O | Mon. 2/m : B2/m |
Gjerdingenite-Fe | K2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O | Mon. 2/m : B2/m |
Gjerdingenite-Mn | K2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O | Mon. 2/m : B2/m |
Gjerdingenite-Na | K2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2O | Mon. 2/m : B2/m |
Kuzmenkoite-Mn | K2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2O | Mon. 2/m : B2/m |
Kuzmenkoite-Zn | K2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2O | Mon. m : Bm |
Lepkhenelmite-Zn | (Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O | Mon. m : Bm |
Common Associates
Associated Minerals Based on Photo Data:
1 photo of Karupmøllerite-Ca associated with Manganoneptunite | KNa2Li(Mn2+)2Ti2[Si4O12]2 |
Related Minerals - Strunz-mindat Grouping
9.CE. | Dutkevichite-(Ce) | NaZnBa2Ce2Ti2Si8O26F · H2O |
9.CE. | Niobobaotite | Ba4(Ti2.5Fe2+1.5)Nb4Si4O28Cl |
9.CE. | Amaterasuite | Sr4Ti6Si4O23(OH)Cl |
9.CE. | Steiningerite | Ba2Zr2(Si4O12)O2 |
9.CE.05 | Papagoite | CaCu[H3AlSi2O9] |
9.CE.10 | Verplanckite | Ba4Mn2+2Si4O12(OH,H2O)3Cl3 |
9.CE.15 | Baotite | Ba4(Ti,Nb,W)8O16(SiO3)4Cl |
9.CE.20 | Nagashimalite | Ba4(V,Ti)4B2Si8O27(O,OH)2Cl |
9.CE.20 | Taramellite | Ba4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2Clx |
9.CE.20 | Titantaramellite | Ba4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2Clx |
9.CE.25 | Bario-orthojoaquinite | (Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2O |
9.CE.25 | Byelorussite-(Ce) | NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2O |
9.CE.25 | Joaquinite-(Ce) | NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2O |
9.CE.25 | Orthojoaquinite-(La) | NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2O |
9.CE.25 | Strontiojoaquinite | Sr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2O |
9.CE.25 | Orthojoaquinite-(Ce) | NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2O |
9.CE.25 | Strontio-orthojoaquinite | (Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2O |
9.CE.30e | Labuntsovite-Mn | Na4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2O |
9.CE.30b | Tsepinite-Na | Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30c | Gjerdingenite-Na | K2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2O |
9.CE.30h | Alsakharovite-Zn | NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30c | Burovaite-Ca | (Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2O |
9.CE.30a | Nenadkevichite | (Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2O |
9.CE.30b | Tsepinite-Sr | Sr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30c | Gjerdingenite-Mn | K2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30b | Paratsepinite-Na | (Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8 · nH2O n ~ 8 |
9.CE.30d | Lemmleinite-K | K2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2O |
9.CE.30c | Lepkhenelmite-Zn | (Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30h | Gutkovaite-Mn | K2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O |
9.CE.30e | Labuntsovite-Mg | Na4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O |
9.CE.30e | Labuntsovite-Fe | Na4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O |
9.CE.30c | Kuzmenkoite-Zn | K2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2O |
9.CE.30f | Paralabuntsovite-Mg | Na8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2O |
9.CE.30d | Lemmleinite-Ba | Na2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O |
9.CE.30g | Organovaite-Mn | K2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2O |
9.CE.30g | Organovaite-Zn | K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30b | Vuoriyarvite-K | K2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2O |
9.CE.30c | Gjerdingenite-Fe | K2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30a | Unnamed (Ca-Na-ordered analogue of Korobitsynite) | (Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O |
9.CE.30g | Parakuzmenkoite-Fe | (K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2O |
9.CE.30a | Korobitsynite | (Na,◻)4Ti2(Si4O12)(O,OH)2 · 4H2O |
9.CE.30c | Kuzmenkoite-Mn | K2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2O |
9.CE.30b | Tsepinite-K | K2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30b | Paratsepinite-Ba | Ba4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2O |
9.CE.30h | Neskevaaraite-Fe | K3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2O |
9.CE.30c | Gjerdingenite-Ca | K2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30b | Tsepinite-Ca | (Ca,K,Na)2-x(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2O |
9.CE.45 | Natrokomarovite | (Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2O |
9.CE.45 | Komarovite | (Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Karupmøllerite-Ca
mindat.org URL:
https://www.mindat.org/min-11159.html
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References for Karupmøllerite-Ca
Reference List:
Pekov, I. V., Chukanov, N. V., Petersen, O. V., Zadov, A. E., Yamnova, N. A., Kabalov, Y. K., Schneider, J. (2002) Karupmøllerite–Ca, (Na,Ca,K)2Ca(Nb,Ti)4 (Si4O12)2(O,OH)4·7H2O, a new mineral of the labuntsovite group from
the Ilímaussaq alkaline complex, South Greenland. Neues Jahrbuch für Mineralogie - Monatshefte, 2002 (10) 433-444 doi:10.1127/0028-3649/2002/2002-0433
Rastsvetaeva, R. K., Chukanov, N. V. (2002) X-ray diffraction and IR spectroscopy study of labuntsovite-group minerals. Crystallography Reports, 47 (6) 939-945 doi:10.1134/1.1523537
Chukanov, Nikita V., Pekov, Igor V., Khomyakov, Alexander P. (2002) Recommended nomenclature for labuntsovite-group minerals. European Journal of Mineralogy, 14 (1) 165-173 doi:10.1127/0935-1221/2002/0014-0165
Pekov, I. V., Chukanov, N. V., Petersen, O. V., Zadov, A. E., Yamnova, N. A., Kabalov, Y. K., Schneider, J. (2002) Karupmøllerite–Ca, (Na,Ca,K)2Ca(Nb,Ti)4 (Si4O12)2(O,OH)4·7H2O, a new mineral of the labuntsovite group from
the Ilímaussaq alkaline complex, South Greenland. Neues Jahrbuch für Mineralogie - Monatshefte, 2002 (10) 433-444 doi:10.1127/0028-3649/2002/2002-0433
Localities for Karupmøllerite-Ca
Locality List




All localities listed without proper references should be considered as questionable.
Greenland | |
| Petersen (2001) |
| Pekov et al. (2002) |
Russia | |
| https://www.mindat.org/photo-54755.html |
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Rischorr Mt, Khibiny Massif, Murmansk Oblast, Russia